1,6-PHENAZINEDIOL5,10-DIOXIDE

Base Information

• Chemical Name: 1,6-PHENAZINEDIOL5,10-DIOXIDE
• CAS No.: 68-81-5
• Molecular Formula: C12H8N2O4
• Molecular Weight: 244.2029
• Mol file: 68-81-5.mol

Synonyms:1,10-dioxide;1,6-dihydroxyphenazine 5,10-dioxide;Crystallojodinin A;1.6-Dihydroxy-phenazin-5.10-dioxyd;Iodinine;1,5,10-dioxide;5,10-dioxy-phenazine-1,6-diol;5,10-Dioxy-phenazin-1,6-diol;Iodinin;

Chemical Property of 1,6-PHENAZINEDIOL5,10-DIOXIDE

Chemical Property:

• Vapor Pressure: 2.81E-13mmHg at 25°C
• Boiling Point: 557.8°Cat760mmHg
• PKA: 12.5(at 25℃)
• Flash Point: 291.1°C
• PSA: 91.38000
• Density: 1.7g/cm³
• LogP: 2.26120

Purity/Quality:

99% ^*data from raw suppliers

IODININ 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,6-PHENAZINEDIOL5,10-DIOXIDE

There total 20 articles about 1,6-PHENAZINEDIOL5,10-DIOXIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

phenazine-1,6-diol (69-48-7) → iodinin (68-81-5)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In toluene; at 70 ℃; for 7h; Solvent; Reagent/catalyst; Time; Temperature; Inert atmosphere;

Reference yield:

phenazine-1,6-diol (69-48-7) → iodinin (68-81-5) + 1,6-dihydroxyphenazine N5-monooxide (69-86-3)

Guidance literature:

With recombinant monooxygenase XpzH; NADPH; flavin adenine dinucleotide; In dimethyl sulfoxide; at 20 ℃; pH=8.5; Enzymatic reaction;

DOI:10.1038/s41589-019-0246-1

Reference yield:

phenazine-1,6-diol (69-48-7) → iodinin (68-81-5) + 1,6-dimethoxy-phenazinol-5-oxide (13925-10-5)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In toluene; at 80 ℃; for 6h; Reagent/catalyst; Solvent; Temperature; Inert atmosphere;

DOI:10.1016/j.bmc.2017.02.058

upstream raw materials:

phenazine-1,6-diol

1-ethoxy-2-nitrobenzene

1,6-diethoxy-phenazine

ortho-phenitidine

Downstream raw materials:

1-hydroxy-6-methoxy-phenazine-N₅,N₁₀-dioxide

1-hydroxy-6-methoxyphenazine N₁₀-oxide

1,6-dimethoxyphenazine-N₅,N 10-dioxide

phenazine-1,6-diol