9-(2-Fluorophenyl)anthracene

Base Information

• Chemical Name: 9-(2-Fluorophenyl)anthracene
• CAS No.: 737-24-6
• Molecular Formula: C20H13F
• Molecular Weight: 272.3156
• NSC Number: 82532
• DSSTox Substance ID: DTXSID50292433
• Nikkaji Number: J2.936.344G
• Wikidata: Q82030734
• Mol file: 737-24-6.mol

Synonyms:9-(2-fluorophenyl)anthracene;737-24-6;NSC 82532;NSC82532;SCHEMBL19426806;DTXSID50292433;NSC-82532

Chemical Property of 9-(2-Fluorophenyl)anthracene

Chemical Property:

• Vapor Pressure: 3.27E-06mmHg at 25°C
• Boiling Point: 398.9°Cat760mmHg
• Flash Point: 192.1°C
• Density: 1.198g/cm³
• XLogP3: 6.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 272.100128577
• Heavy Atom Count: 21
• Complexity: 330

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C=C3C=CC=CC3=C2C4=CC=CC=C4F

Technology Process of 9-(2-Fluorophenyl)anthracene

There total 3 articles about 9-(2-Fluorophenyl)anthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

9-Bromoanthracene (1564-64-3) + o-fluorophenylboronic acid (1993-03-9) → 9-(2-fluorophenyl)anthracene (737-24-6)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In ethanol; toluene; for 24h; Inert atmosphere; Reflux; Sealed tube;

DOI:10.1021/jacs.9b03328

Reference yield:

2'-Fluor-2-benzyl-benzophenon (740-35-2) → 9-(2-fluorophenyl)anthracene (737-24-6)

Guidance literature:

With hydrogen bromide; acetic acid; at 150 ℃;

DOI:10.1021/jo01082a005

Reference yield:

→ 9-(2-fluorophenyl)anthracene (737-24-6)

Guidance literature:

2'-Fluor-2-benzyl-benzophenon (polarograph. Unters. d. Kinetik);

DOI:10.1021/jo01256a025

upstream raw materials:

2'-Fluor-2-benzyl-benzophenon

9-Bromoanthracene

o-fluorophenylboronic acid