Boranamine, N-[2,6-bis(1-methylethyl)phenyl]-1-chloro-1-phenyl-

Base Information

• Chemical Name: Boranamine, N-[2,6-bis(1-methylethyl)phenyl]-1-chloro-1-phenyl-
• CAS No.: 681851-62-7
• Molecular Formula: C₁₈H₂₃BClN
• Molecular Weight: 299.651
• Mol file: 681851-62-7.mol

Synonyms:

Chemical Property of Boranamine, N-[2,6-bis(1-methylethyl)phenyl]-1-chloro-1-phenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Boranamine, N-[2,6-bis(1-methylethyl)phenyl]-1-chloro-1-phenyl-

There total 1 articles about Boranamine, N-[2,6-bis(1-methylethyl)phenyl]-1-chloro-1-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

2,6-diisopropylbenzenamine (24544-04-5) + phenylborondichloride (873-51-8) → PhBCl(N(H)Dipp)] (681851-62-7)

Guidance literature:

In diethyl ether; under Ar atm. soln. DippNH2 in Et2O was added to soln. PhBCl2 in Et2O at-40°C, react. mixt. was allowed to warm slowly to room temp. and stirred for 2 h; soln. was filtered and evapd. in vacuo; elem. anal.;

DOI:10.1021/ic0352755

Reference yield: 88.0%

PhBCl(N(H)Dipp)] (681851-62-7) + Li[C(NtBu)2nBu] → ([DippN(H)](Ph)B(μ-N(t)Bu)2C(n)Bu)

Guidance literature:

In hexane; byproducts: LiCl; under Ar atm. soln. PhBCl(N(H)Dipp) in n-hexane was added to Li((n)BuC(N(t)Bu)2) in n-hexane at -78°C, react. mixt. was allowed to warm to room temp. and stirred for 18 h; soln. was filtered and evapd. in vacuo; elem. anal.;

DOI:10.1021/ic0352755

Reference yield: 76.0%

lithium N,N'-bis(2,6-di-isopropylphenyl)tert-butylamidinate + PhBCl(N(H)Dipp)] (681851-62-7) → ([DippN(H)PhB(NDipp)C(n)Bu(NDipp)) (681851-66-1)

Guidance literature:

In hexane; byproducts: LiCl; under Ar atm. soln. PhBCl(N(H)Dipp) in n-hexane was added to soln. Li((n)BuC(NDipp)2) in n-hexane at -78°C, allowed to warm slowly to room temp. and stirred for 18 h; soln. was filtered and evapd. in vacuo; elem. anal.;

DOI:10.1021/ic0352755

upstream raw materials:

2,6-diisopropylbenzenamine

phenylborondichloride

Downstream raw materials:

PhB[N(H)Dipp][N(H)(t)Bu]

([DippN(H)PhB(NDipp)C(n)Bu(NDipp))