Dendrolasin

Base Information

• Chemical Name: Dendrolasin
• CAS No.: 23262-34-2
• Molecular Formula: C15H22 O
• Molecular Weight: 218.339
• Hs Code.: 2932190090
• DSSTox Substance ID: DTXSID501318273
• Nikkaji Number: J16.577H
• Wikidata: Q27149763
• Metabolomics Workbench ID: 47175
• Mol file: 23262-34-2.mol

Synonyms:dendrolasin

Chemical Property of Dendrolasin

Chemical Property:

• Vapor Pressure: 0.0017mmHg at 25°C
• Boiling Point: 303.2°Cat760mmHg
• Flash Point: 130.8°C
• PSA: 13.14000
• Density: 0.908g/cm³
• LogP: 4.90490
• XLogP3: 5.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 6
• Exact Mass: 218.167065321
• Heavy Atom Count: 16
• Complexity: 246

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=CCCC(=CCCC1=COC=C1)C)C
• Isomeric SMILES: CC(=CCC/C(=C/CCC1=COC=C1)/C)C

Technology Process of Dendrolasin

There total 5 articles about Dendrolasin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

(furan-3-ylmethyl)magnesium chloride (85757-86-4) + 1-chloro-3,7-dimethylocta-2,6-diene (5389-87-7) → dendrolasin (23262-34-2)

Guidance literature:

With dilithium tetrachlorocuprate; In tetrahydrofuran;

DOI:10.1016/S0040-4039(00)88573-1

Reference yield:

trans-geranyl bromide (6138-90-5) + (3-furylmethyl)magnesium bromide (81719-68-8) → sesquirosefuran (39007-93-7) + 3-(2,6-dimethyl-2-vinyl-5-heptenyl)furan (81719-67-7) + dendrolasin (23262-34-2)

Guidance literature:

copper(l) iodide; Yield given. Yields of byproduct given; 1.) -78 deg C; 2.) room temp;

DOI:10.1246/cl.1982.177

Reference yield:

(E)-3,7-dimethylocta-2,6-dien-1-yl diethyl phosphate (60699-32-3) + (3-furylmethyl)magnesium bromide (81719-68-8) → sesquirosefuran (39007-93-7) + 3-(2,6-dimethyl-2-vinyl-5-heptenyl)furan (81719-67-7) + dendrolasin (23262-34-2)

Guidance literature:

Yield given. Yields of byproduct given; 1.) -78 deg C; 2.) room temp;

DOI:10.1246/cl.1982.177

upstream raw materials:

trans-geranyl bromide

(3-furylmethyl)magnesium bromide

(furan-3-ylmethyl)magnesium chloride

1-chloro-3,7-dimethylocta-2,6-diene

Downstream raw materials:

9-(3-furyl)-2,6-dimethyl-3-phenylthionona-1,6(E)-diene

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