Tricyclo(8.2.2.24,7)hexadeca-4,6,10,12,13,15-hexaene, 5,6,11,12,13-pentamethyl-

Base Information

Chemical Name:Tricyclo(8.2.2.24,7)hexadeca-4,6,10,12,13,15-hexaene, 5,6,11,12,13-pentamethyl-
CAS No.:77897-14-4
Molecular Formula:C₂₁H₂₆
Molecular Weight:278.437
Hs Code.:
DSSTox Substance ID:DTXSID20228522
Wikidata:Q83108514

Synonyms:Tricyclo(8.2.2.24,7)hexadeca-4,6,10,12,13,15-hexaene, 5,6,11,12,13-pentamethyl-;77897-14-4;Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene, 5,6,11,12,13-pentamethyl-;DTXSID20228522;2,3,5,5',6'-Pentamethyl[2.2]paracyclophane

Suppliers and Price of Tricyclo(8.2.2.24,7)hexadeca-4,6,10,12,13,15-hexaene, 5,6,11,12,13-pentamethyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Tricyclo(8.2.2.24,7)hexadeca-4,6,10,12,13,15-hexaene, 5,6,11,12,13-pentamethyl-

Chemical Property:

Vapor Pressure:1.67E-06mmHg at 25°C
Boiling Point:408.3°Cat760mmHg
Flash Point:221.9°C
Density:0.984g/cm³
XLogP3:6.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:0
Exact Mass:278.203450829
Heavy Atom Count:21
Complexity:346

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC2=C(C(=C1CCC3=C(C(=C(CC2)C=C3)C)C)C)C

Technology Process of Tricyclo(8.2.2.24,7)hexadeca-4,6,10,12,13,15-hexaene, 5,6,11,12,13-pentamethyl-

There total 9 articles about Tricyclo(8.2.2.24,7)hexadeca-4,6,10,12,13,15-hexaene, 5,6,11,12,13-pentamethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 15-Bromomethyl-5,6,13,14-tetramethyl-tricyclo[8.2.2.2^4,7]hexadeca-1⁽¹³⁾,4⁽¹⁶⁾,5,7⁽¹⁵⁾,10⁽¹⁴⁾,11-hexaene

: 77897-14-4
4,5,7,12,13-pentamethyl<2.2>paracyclophane

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran;
DOI:10.1016/S0040-4039(00)71150-6

Reference yield: 53.0%

: 77910-12-4
4-formyl-7,8,15,16-tetramethyl<2.2>paracyclophane

: 77897-15-5
Acetic acid 13,14,15,16-tetramethyl-tricyclo[8.2.2.2^4,7]hexadeca-1⁽¹³⁾,4,6,10⁽¹⁴⁾,11,15-hexaen-5-ylmethyl ester

: 77897-14-4
4,5,7,12,13-pentamethyl<2.2>paracyclophane

Guidance literature:: With hydrogen; palladium on activated charcoal; In acetic acid; for 92h;
DOI:10.1016/S0040-4039(00)71150-6

Reference yield:

: 102419-27-2,69684-86-2,37437-92-6
4,5,12,13-tetrakis(hydroxymethyl)<2.2>paracyclophane

: 77897-14-4
4,5,7,12,13-pentamethyl<2.2>paracyclophane

Guidance literature:: Multi-step reaction with 6 steps

1: 90 percent / PBr₃

2: 89 percent / LAH / tetrahydrofuran

3: 92 percent / TiCl₄ / 0 °C

4: 93 percent / LAH / tetrahydrofuran

5: 92 percent / PBr₃ / CH₂Cl₂

6: 88 percent / LAH / tetrahydrofuran

With lithium aluminium tetrahydride; phosphorus tribromide; titanium tetrachloride; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4039(00)71150-6