dichloroplatinum(2+) (Z)-phenylethenediide - pyridine (1:1:1)

Base Information

• Chemical Name: dichloroplatinum(2+) (Z)-phenylethenediide - pyridine (1:1:1)
• CAS No.: 60117-59-1
• Molecular Formula: C13H11Cl2NPt
• Molecular Weight: 449.239
• Mol file: 60117-59-1.mol

Synonyms:

Chemical Property of dichloroplatinum(2+) (Z)-phenylethenediide - pyridine (1:1:1)

Chemical Property:

• Vapor Pressure: 6.21mmHg at 25°C
• Boiling Point: 145.2°Cat760mmHg
• Flash Point: 31.1°C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichloroplatinum(2+) (Z)-phenylethenediide - pyridine (1:1:1)

There total 4 articles about dichloroplatinum(2+) (Z)-phenylethenediide - pyridine (1:1:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

{platinum(μ-Cl)Cl(PhCHCH2)}2 → π-(styrene)PtCl2(pyridine) (60117-59-1)

Guidance literature:

With pyridine; In chloroform; water; aq. soln. of pyridine added to a soln. of Pt-complex in CHCl3; evapd.; chromy.;

DOI:10.1007/BF00953114

Reference yield: 50.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + sodium hexachloroplatinate(IV) hexahydrate → π-(styrene)PtCl2(pyridine) (60117-59-1)

Guidance literature:

With pyridine; In acetone; Irradiation (UV/VIS); soln. of educts was irradiated for 15 min., acetone was removed under reduced pressure, the residue was extracted with CH3Cl and the soln. was treated with aq. pyridine.;; chromy. (SiO2);

DOI:10.1016/0022-328X(84)85063-9

Reference yield: 18.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + dihydrogen hexachloroplatinate(IV) hexahydrate → π-(styrene)PtCl2(pyridine) (60117-59-1)

Guidance literature:

With pyridine; In water; acetic acid; educts were heated at 120 °C for 10 min.,the solvent was evaptd., the residue was extracted with CH3Cl, and the soln. was shaken with aq. pyridine.;; chromy.(SiO2);

DOI:10.1016/0022-328X(84)85063-9

upstream raw materials:

styrene

hexachloroplatinate(II)

Downstream raw materials:

styrene

trans-(py)PtCl₂(CH₂=CH-C₆H₄-m-Cl)

trans-(py)PtCl₂(CH₂=CH-C₆H₄-m-Me)