5-Bromo-2-methylbenzenethiol

Base Information

Chemical Name:5-Bromo-2-methylbenzenethiol
CAS No.:69321-55-7
Molecular Formula:C7H7BrS
Molecular Weight:203.103
Hs Code.:
European Community (EC) Number:865-668-5

Synonyms:5-Bromo-2-methylbenzenethiol;69321-55-7;5-Bromo-2-methylbenzene-1-thiol;SCHEMBL5424955;SFFDMQAUOUPZMM-UHFFFAOYSA-N;AT20875;CS-0257551;EN300-673792

Suppliers and Price of 5-Bromo-2-methylbenzenethiol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 5-Bromo-2-methylbenzenethiol

Chemical Property:

XLogP3:3.1
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:201.94518
Heavy Atom Count:9
Complexity:94.9

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=C(C=C(C=C1)Br)S

Technology Process of 5-Bromo-2-methylbenzenethiol

There total 5 articles about 5-Bromo-2-methylbenzenethiol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 1093847-06-3
S-5-bromo-2-methylphenyl O-ethylcarbonodithioate

: 69321-55-7
5-bromo-2-methylbenzenethiol

Guidance literature:: S-5-bromo-2-methylphenyl O-ethylcarbonodithioate; With potassium hydroxide; In ethanol; for 5h; Reflux;

With hydrogenchloride; In ethanol; water;
DOI:10.1039/c3ob40250a

Reference yield: 73.0%

: 39478-78-9
5-bromo-2-methylaniline

: 69321-55-7
5-bromo-2-methylbenzenethiol

Guidance literature:: 5-bromo-2-methylaniline; With hydrogenchloride; sodium nitrite; In water; at -10 - -5 ℃; for 0.666667h;

With potassium ethyl xanthogenate; In water; at 65 ℃; for 0.833333h;

With potassium hydroxide; In ethanol; for 18h; Reflux;

Reference yield:

: 60956-26-5
4-bromo-2-nitrotoluene

: 69321-55-7
5-bromo-2-methylbenzenethiol

Guidance literature:: Multi-step reaction with 2 steps

1.1: hydrogenchloride; sodium nitrite / water / 2.5 h / 0 °C / Reflux

1.2: 1 h

2.1: potassium hydroxide / ethanol / 5 h / Reflux

With hydrogenchloride; potassium hydroxide; sodium nitrite; In ethanol; water;
DOI:10.1039/c3ob40250a