Benzene, 1,1'-tellurobis[2,4,6-trimethyl-

Base Information

• Chemical Name: Benzene, 1,1'-tellurobis[2,4,6-trimethyl-
• CAS No.: 70165-32-1
• Molecular Formula: C18H22Te
• Molecular Weight: 365.973
• DSSTox Substance ID: DTXSID30472554
• Nikkaji Number: J465.873F
• Wikidata: Q82301532
• Mol file: 70165-32-1.mol

Synonyms:Benzene, 1,1'-tellurobis[2,4,6-trimethyl-;70165-32-1;DTXSID30472554

Chemical Property of Benzene, 1,1'-tellurobis[2,4,6-trimethyl-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 368.0783734
• Heavy Atom Count: 19
• Complexity: 235

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1=CC(=C(C(=C1)C)[Te]C2=C(C=C(C=C2C)C)C)C

Technology Process of Benzene, 1,1'-tellurobis[2,4,6-trimethyl-

There total 12 articles about Benzene, 1,1'-tellurobis[2,4,6-trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

tris(2,4,6-trimethylphenyl)bismuth (59344-64-8) → bis(2,4,6-trimethylphenyl) telluride (70165-32-1) + dimesityl ditelluride (92720-46-2)

Guidance literature:

With tellurium; In toluene; for 24h; Heating;

DOI:10.1021/jo982093x

Reference yield: 84.0%

mesityltellurium(II) bromide + 2-mesitylmagnesium bromide (2633-66-1) → bis(2,4,6-trimethylphenyl) telluride (70165-32-1)

Guidance literature:

In tetrahydrofuran; toluene; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1039/c4dt02200a

Reference yield: 84.0%

bromine (10097-32-2) + dimesityl ditelluride (92720-46-2) + 2-mesitylmagnesium bromide (2633-66-1) → bis(2,4,6-trimethylphenyl) telluride (70165-32-1)

Guidance literature:

bromine; dimesityl ditelluride; In toluene; Cooling with ice; Inert atmosphere;

2-mesitylmagnesium bromide; In tetrahydrofuran; toluene; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1021/acs.inorgchem.5b02024

upstream raw materials:

2-mesitylmagnesium bromide

iodomesitylene

dimesityl ditelluride

tris(2,4,6-trimethylphenyl)bismuth

Downstream raw materials:

C₂₇H₂₆PTe⁽¹⁺⁾*CF₃O₃S^(1-)

C₂₇H₂₆AsTe⁽¹⁺⁾*CF₃O₃S^(1-)

C₂₇H₃₃Te₂⁽¹⁺⁾*CF₃O₃S^(1-)

[2,4,6-Me₃C₆H₂Te(Sb(phenyl)₃)][(phenyl)₂Sb(triflate)₂]