(E)-3,9-Dimethyl-6-isopropyl-5,8-decadien-1-ol acetate

Base Information

Chemical Name:(E)-3,9-Dimethyl-6-isopropyl-5,8-decadien-1-ol acetate
CAS No.:71524-58-8
Molecular Formula:C17H30O2
Molecular Weight:266.41900
Hs Code.:
Mol file:71524-58-8.mol

Synonyms:Acetic acid (E)-6-isopropyl-3,9-dimethyl-deca-5,8-dienyl ester;(E)-6-isopropyl-3,9-dimethyl-5,8-decadienyl acetate;yellowscale pheromone;E-6-isopropyl-3,9-dimethyl-5,8-decadienyl acetate;E-3,9-Dimethyl-6-isopropyl-5,8-decadien-1-yl-acetat;

Suppliers and Price of (E)-3,9-Dimethyl-6-isopropyl-5,8-decadien-1-ol acetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of (E)-3,9-Dimethyl-6-isopropyl-5,8-decadien-1-ol acetate

Chemical Property:

PSA：26.30000
LogP:4.90450

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (E)-3,9-Dimethyl-6-isopropyl-5,8-decadien-1-ol acetate

There total 38 articles about (E)-3,9-Dimethyl-6-isopropyl-5,8-decadien-1-ol acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 108-24-7
acetic anhydride

: 78849-02-2
(E)-6-isopropyl-3,9-dimethyl-5,8-decadien-1-ol

: 71524-58-8
(E)-6-isopropyl-3,9-dimethyl-5,8-decadienyl acetate

Guidance literature:: With pyridine; for 2h; Ambient temperature;

Reference yield:

: 142011-65-2
(E)-1-tert-butyldimethylsiloxy-3-iodo-4-methyl-2-pentene

: 71524-58-8
(E)-6-isopropyl-3,9-dimethyl-5,8-decadienyl acetate

Guidance literature:: Multi-step reaction with 7 steps

1: 1.) tert-BuLi / 1.) ether/pentane, -78 deg C, 70 min, 2.) ether/pentane, -78 deg C, 1 h

2: 91 percent / (TMS)2NLi / tetrahydrofuran / Ambient temperature

3: 97 percent / tetrabutylammonium fluoride / tetrahydrofuran / 0 °C

4: 1.) oxalyl chloride, DMSO, 3.) Et₃N / 1.) CH₂Cl₂, -78 deg C, 15 min, 2.) CH₂Cl₂, -78 deg C, 25 min, 3.) CH₂Cl₂, 0 deg C, 25 min

5: 1.) n-BuLi / 1.) hexane/ether, room temperature, 2 h, 2.) hexane/ether, 17 h, room temperature

6: lithium, acetic acid, isoprene / tetrahydrofuran; liquid ammonia / -78 °C

7: 4-DMAP / CH₂Cl₂ / Ambient temperature

With dmap; n-butyllithium; oxalyl dichloride; tetrabutyl ammonium fluoride; tert.-butyl lithium; lithium; acetic acid; dimethyl sulfoxide; triethylamine; lithium hexamethyldisilazane; isoprene; In tetrahydrofuran; dichloromethane; ammonia;
DOI:10.1016/S0040-4020(01)87241-0

Reference yield:

: 142011-69-6
(Z)-4-hydroxymethyl-5-isopropyl-8-methyl-7,8,9,10-tetrahydro-4H-1,3-oxathiecin-2-one

: 71524-58-8
(E)-6-isopropyl-3,9-dimethyl-5,8-decadienyl acetate

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) oxalyl chloride, DMSO, 3.) Et₃N / 1.) CH₂Cl₂, -78 deg C, 15 min, 2.) CH₂Cl₂, -78 deg C, 25 min, 3.) CH₂Cl₂, 0 deg C, 25 min

2: 1.) n-BuLi / 1.) hexane/ether, room temperature, 2 h, 2.) hexane/ether, 17 h, room temperature

3: lithium, acetic acid, isoprene / tetrahydrofuran; liquid ammonia / -78 °C

4: 4-DMAP / CH₂Cl₂ / Ambient temperature

With dmap; n-butyllithium; oxalyl dichloride; lithium; acetic acid; dimethyl sulfoxide; triethylamine; isoprene; In tetrahydrofuran; dichloromethane; ammonia;
DOI:10.1016/S0040-4020(01)87241-0