{1-[(4-Chlorophenyl)sulfanyl]ethenyl}(trimethyl)silane

Base Information

Chemical Name:{1-[(4-Chlorophenyl)sulfanyl]ethenyl}(trimethyl)silane
CAS No.:72622-67-4
Molecular Formula:C11H15ClSSi
Molecular Weight:242.845
Hs Code.:
DSSTox Substance ID:DTXSID50504184
Wikidata:Q82358500

Synonyms:72622-67-4;{1-[(4-Chlorophenyl)sulfanyl]ethenyl}(trimethyl)silane;DTXSID50504184

Suppliers and Price of {1-[(4-Chlorophenyl)sulfanyl]ethenyl}(trimethyl)silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of {1-[(4-Chlorophenyl)sulfanyl]ethenyl}(trimethyl)silane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:242.0352259
Heavy Atom Count:14
Complexity:202

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)C(=C)SC1=CC=C(C=C1)Cl

Technology Process of {1-[(4-Chlorophenyl)sulfanyl]ethenyl}(trimethyl)silane

There total 3 articles about {1-[(4-Chlorophenyl)sulfanyl]ethenyl}(trimethyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 5.0%

: 72610-22-1
2-chloro-1-(trimethylsilyl)ethyl 4-chlorophenyl sulfide

: 72622-67-4
1-(trimethylsilyl)-1-<(4-chlorophenyl)thio>ethylene

: 16411-16-8
p-chlorophenyl vinyl sulfide

Guidance literature:: With DBN; In diethyl ether; for 12h; 1. 0 deg C; 2. 20 deg C, 12 h;
DOI:10.1021/jo01294a026

Reference yield:

: 106-54-7
p-Chlorothiophenol

: 72622-67-4
1-(trimethylsilyl)-1-<(4-chlorophenyl)thio>ethylene

Guidance literature:: Multi-step reaction with 3 steps

1: N-chlorosuccinimide / CH₂Cl₂ / Heating

2: CH₂Cl₂ / 1. -78 deg C; 2. 20 deg C, 2 h

3: 80.3 percent / 1,5-diazabicyclo<4.3.0>non-5-ene / diethyl ether / 12 h / 1. 0 deg C; 2. 20 deg C, 12 h

With N-chloro-succinimide; DBN; In diethyl ether; dichloromethane;
DOI:10.1021/jo01294a026

Reference yield:

: 933-01-7
4-chloro-benzenesulfenyl chloride

: 72622-67-4
1-(trimethylsilyl)-1-<(4-chlorophenyl)thio>ethylene

Guidance literature:: Multi-step reaction with 2 steps

1: CH₂Cl₂ / 1. -78 deg C; 2. 20 deg C, 2 h

2: 80.3 percent / 1,5-diazabicyclo<4.3.0>non-5-ene / diethyl ether / 12 h / 1. 0 deg C; 2. 20 deg C, 12 h

With DBN; In diethyl ether; dichloromethane;
DOI:10.1021/jo01294a026