[(Chlorogallanediyl)bis(methylene)]bis(trimethylsilane)

Base Information

Chemical Name:[(Chlorogallanediyl)bis(methylene)]bis(trimethylsilane)
CAS No.:72708-38-4
Molecular Formula:2C₄H₁₁Si*Cl*Ga
Molecular Weight:279.61
Hs Code.:
DSSTox Substance ID:DTXSID90556440
Wikidata:Q82437994

Synonyms:72708-38-4;[(Chlorogallanediyl)bis(methylene)]bis(trimethylsilane);DTXSID90556440

Suppliers and Price of [(Chlorogallanediyl)bis(methylene)]bis(trimethylsilane)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [(Chlorogallanediyl)bis(methylene)]bis(trimethylsilane)

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:4
Exact Mass:278.02043
Heavy Atom Count:12
Complexity:121

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)C[Ga](C[Si](C)(C)C)Cl

Technology Process of [(Chlorogallanediyl)bis(methylene)]bis(trimethylsilane)

There total 1 articles about [(Chlorogallanediyl)bis(methylene)]bis(trimethylsilane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.5%

: 72708-53-3
tris(trimethylsilylmethyl)gallium

: 72708-38-4,72708-39-5
((trimethylsilyl)methyl)gallium(III) chloride

: 75-76-3
tetramethylsilane

: Ga₂⁽⁶⁺⁾*2CH₂Si(CH₃)3^(1-)*4Cl^(1-)=[GaCl₂(CH₂Si(CH₃)3)]2

Guidance literature:: With HCl; In benzene; HCl added in three equimolar portions by vac. distn. at -196°C, after each addn. mixt. warmed to room temp. and stirred for 1 h; volatile products fractionally distd., nonvolatile products extd. with n-pentane, insol. component collected, identified as Ga(CH2SiMe3)2Cl (elem. anal.), sol. fraction mixt. of Ga(CH2SiMe3)Cl2 and Ga(CH2SiMe3)3;
DOI:10.1021/ic50206a046

Reference yield: 94.5%

: 72708-38-4
bis(trimethylsilylmethoxy)galliumchloride

: 62263-69-8
(lithiomethyl)diphenylphosphane

: 184477-88-1
((CH₃)3SiCH₂)2Ga(CH₂P(C₆H₅)2)

Guidance literature:: In pentane; byproducts: LiCl; (Ar); Ga-compound dissolved in pentane and cooled to -78°C, LiCH2PPh2 added slowly with stirring (15 min), warmed to room temp. and stirred for 18 h; solvent removed, extd. (C6H6/pentane), recrystd. (C6H6); elem.anal.;