Propenoic acid 3-methyl-2-butenyl ester

Base Information

• Chemical Name: Propenoic acid 3-methyl-2-butenyl ester
• CAS No.: 72879-37-9
• Molecular Formula: C₈H₁₂O₂
• Molecular Weight: 140.182
• Mol file: 72879-37-9.mol

Synonyms:Acrylic acid 3-methyl-but-2-enyl ester;

Chemical Property of Propenoic acid 3-methyl-2-butenyl ester

Chemical Property:

• PSA: 26.30000
• LogP: 1.68180

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Propenoic acid 3-methyl-2-butenyl ester

There total 2 articles about Propenoic acid 3-methyl-2-butenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) + 3-methyl-2-buten-1-ol (556-82-1) → prenyl acrylate (72879-37-9)

Guidance literature:

Novozym 435; at 40 ℃; for 6h; Conversion of starting material; Molecular sieve; Enzymatic reaction;

Reference yield:

3-methyl-2-buten-1-yl α-diazopropionate → prenyl acrylate (72879-37-9) + (1R,5R)-1,6,6-Trimethyl-3-oxa-bicyclo[3.1.0]hexan-2-one + (1S,5S)-1,6,6-Trimethyl-3-oxa-bicyclo[3.1.0]hexan-2-one

Guidance literature:

With dirhodium(II) tetrakis In dichloromethane; Yield given. Yields of byproduct given. Title compound not separated from byproducts; Heating;

DOI:10.1016/0957-4166(95)00289-2

upstream raw materials:

acrylic acid methyl ester

3-methyl-2-buten-1-ol

Refernces

• 1、 -. "TRANSESTERIFICATION PROCESS USING MIXED SALT ACETYLACETONATES CATALYSTS". Paragraph 0064; 0065. . Retrieved 2013/04/13.