2-[(E)-(4-Bromophenyl)diazenyl]-1-methyl-1H-imidazole

Base Information

Chemical Name:2-[(E)-(4-Bromophenyl)diazenyl]-1-methyl-1H-imidazole
CAS No.:72908-93-1
Molecular Formula:C₁₀H₉BrN₄
Molecular Weight:265.112
Hs Code.:
DSSTox Substance ID:DTXSID70503053
Nikkaji Number:J1.972.124H

Synonyms:72908-93-1;2-[(E)-(4-Bromophenyl)diazenyl]-1-methyl-1H-imidazole;DTXSID70503053

Suppliers and Price of 2-[(E)-(4-Bromophenyl)diazenyl]-1-methyl-1H-imidazole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-[(E)-(4-Bromophenyl)diazenyl]-1-methyl-1H-imidazole

Chemical Property:

XLogP3:2.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:264.00106
Heavy Atom Count:15
Complexity:226

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CN1C=CN=C1N=NC2=CC=C(C=C2)Br

Technology Process of 2-[(E)-(4-Bromophenyl)diazenyl]-1-methyl-1H-imidazole

There total 1 articles about 2-[(E)-(4-Bromophenyl)diazenyl]-1-methyl-1H-imidazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 72908-93-1
N⁽¹⁾-methyl-2-(4'-bromophenylazo)imidazole

Guidance literature:: 2-(p-Brom-phenylazo)-imidazol (III), Methyliodid;

Reference yield: 60.0%

: 72908-93-1
N⁽¹⁾-methyl-2-(4'-bromophenylazo)imidazole

: 75-05-8,26809-02-9
acetonitrile

: 13939-06-5,199620-15-0
molybdenum hexacarbonyl

: cis-dicarbonylbis(N⁽¹⁾-methyl-2-(4'-bromophenylazo)imidazole)

Guidance literature:: In hexane; Mo(CO)6 refluxed in MeCN; monitored by IR spectra; solvent removed undervac.; hexane and ligand (2 equiv.) added; refluxed for 16 h; solvent removed under vac.; dissolved in CH2Cl2; filtered through Celite; hexane added to filtrate; vol. reduced under vac.; liq. removed; crystals washed with hexane; dried under vac.; elem. anal.;
DOI:10.1016/S0022-328X(03)00793-9

Reference yield: 59.0%

: 12146-37-1,124717-04-0
(bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum⁽⁰⁾

: 72908-93-1
N⁽¹⁾-methyl-2-(4'-bromophenylazo)imidazole

: 633337-05-0
cis-tetracarbonyl(N⁽¹⁾-methyl-2-(4'-bromophenylazo)imidazole)

Guidance literature:: In hexane; mixt. of Mo complex and ligand (molar ratio 1:1) stirred in hexane at room temp.; monitored by IR spectroscopy; solvent removed under reduced pressure; dissolved in CH2Cl2; filtered through Celite; hexane added to filtrate; vol. reduced under vac.; liq. removed; crystals washed with hexane; dried under vac.; elem. anal.;
DOI:10.1016/S0022-328X(03)00793-9