1-Butanol, 3-methyl-4-(phenylmethoxy)-, (R)-

Base Information

Chemical Name:1-Butanol, 3-methyl-4-(phenylmethoxy)-, (R)-
CAS No.:73408-07-8
Molecular Formula:C12H18O2
Molecular Weight:194.274
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-Butanol, 3-methyl-4-(phenylmethoxy)-, (R)-

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Technology Process of 1-Butanol, 3-methyl-4-(phenylmethoxy)-, (R)-

There total 5 articles about 1-Butanol, 3-methyl-4-(phenylmethoxy)-, (R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.5%

: 90865-70-6
[3R]-4-Benzyloxy-3-methylbutanal

: 73408-07-8
(R)-4-(Benzyloxy)-3-methylbutan-1-ol

Guidance literature:: With sodium tetrahydroborate; In ethanol; for 1h; 0 deg C to RT;
DOI:10.1002/hlca.19900730517

Reference yield:

: 917-54-4
methyllithium

: (((4-bromobut-2-en-1-yl)oxy)methyl)benzene

: 73408-07-8
(R)-4-(Benzyloxy)-3-methylbutan-1-ol

: 132364-23-9
(+)-(S)-4-benzyloxy-3-methylbutan-1-ol

Guidance literature:: methyllithium; (((4-bromobut-2-en-1-yl)oxy)methyl)benzene; With copper(I) bromide dimethylsulfide complex; (+)-(R,R_p)-taniaphos; In dichloromethane; toluene; at -80 ℃; for 4h; Schlenk technique; Inert atmosphere;

With 9-borabicyclo[3.3.1]nonane; In tetrahydrofuran; at 20 ℃; for 2h; Schlenk technique; Inert atmosphere;

With dihydrogen peroxide; sodium hydroxide; In ethanol; water; at 0 - 20 ℃; Overall yield = 74 %; Overall yield = 26 mg; enantioselective reaction; Schlenk technique; Inert atmosphere;
DOI:10.1021/jo401536u

Reference yield:

: C₂₀H₁₉NO₄

: 73408-07-8
(R)-4-(Benzyloxy)-3-methylbutan-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1: copper(I) bromide dimethylsulfide complex / tetrahydrofuran; dimethylsulfide

2: lithium borohydride / tetrahydrofuran; water

With lithium borohydride; copper(I) bromide dimethylsulfide complex; In tetrahydrofuran; dimethylsulfide; water;
DOI:10.1055/s-0031-1290082