1,3,5-Benzenetricarboxylic acid, triphenyl ester

Base Information

• Chemical Name: 1,3,5-Benzenetricarboxylic acid, triphenyl ester
• CAS No.: 7383-70-2
• Molecular Formula: C₂₇H₁₈O₆
• Molecular Weight: 438.436
• Mol file: 7383-70-2.mol

Synonyms:

Chemical Property of 1,3,5-Benzenetricarboxylic acid, triphenyl ester

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,3,5-Benzenetricarboxylic acid, triphenyl ester

There total 3 articles about 1,3,5-Benzenetricarboxylic acid, triphenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

phenyl prop-2-ynoate (60998-71-2) + aniline (62-53-3) → triphenyl benzene-1,3,5-tricarboxylate (7383-70-2) + C33H25NO6 + C32H23NO6 + (2E,4Z)-diphenyl 4-[(phenylamino)methylene]pent-2-enedioate

Guidance literature:

With silica gel; In neat (no solvent); at 100 ℃; for 1h; Sealed tube; Green chemistry;

DOI:10.1002/asia.201800645

Reference yield:

1,3,5-benzene tris(carbonyl chloride) (4422-95-1) + sodium phenoxide (139-02-6) → triphenyl benzene-1,3,5-tricarboxylate (7383-70-2)

Guidance literature:

In diethylene glycol dimethyl ether; at 35 ℃; for 24h;

DOI:10.1021/j100058a011

Reference yield:

→ triphenyl benzene-1,3,5-tricarboxylate (7383-70-2)

Guidance literature:

Trimesoylchlorid, Phenol;

upstream raw materials:

1,3,5-benzene tris(carbonyl chloride)

sodium phenoxide

phenyl prop-2-ynoate

aniline

Refernces

• 1、 Aleksi?, Jovana,Stojanovi?, Milovan,Baranac-Stojanovi?, Marija. "Silica Gel as a Promoter of Sequential Aza-Michael/Michael Reactions of Amines and Propiolic Esters: Solvent- and Metal-Free Synthesis of Polyfunctionalized Conjugated Dienes". . p. 1811 - 1835. Retrieved 2018/07/29.