Benzoic acid, 2-hydroxy-6-(1-methylethoxy)-, methyl ester

Base Information

Chemical Name:Benzoic acid, 2-hydroxy-6-(1-methylethoxy)-, methyl ester
CAS No.:74292-72-1
Molecular Formula:C11H14O4
Molecular Weight:210.23
Hs Code.:

Synonyms:

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Chemical Property of Benzoic acid, 2-hydroxy-6-(1-methylethoxy)-, methyl ester

Chemical Property:

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Technology Process of Benzoic acid, 2-hydroxy-6-(1-methylethoxy)-, methyl ester

There total 1 articles about Benzoic acid, 2-hydroxy-6-(1-methylethoxy)-, methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 2150-45-0
methyl 2,6-dihydroxybenzoate

: 67-63-0,8013-70-5
isopropyl alcohol

: 74292-72-1
methyl 2-hydroxy-6-isopropoxybenzoate

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; at 25 ℃;
DOI:10.1016/S0040-4039(00)71469-9

Reference yield:

: 74292-72-1
methyl 2-hydroxy-6-isopropoxybenzoate

: 129929-72-2
2-(2-bromomethyl-3-isopropoxyphenoxy)-3-isopropoxy-5-methoxy-4-methylbenzyl bromide

Guidance literature:: Multi-step reaction with 8 steps

1: 92 percent / lithium aluminium hydride / diethyl ether / 15 h / Ambient temperature

2: 83 percent / manganese dioxide / diethyl ether / 30 h / Ambient temperature

3: 71 percent / potassium carbonate / diethyl ether / 35 h

4: 68 percent / toluene p-sulphonic acid / benzene / 1 h / Heating

5: 73 percent / lithium aluminium hydride / tetrahydrofuran / 1 h / 0 °C

6: 26 percent / pyridine, potassium carbonate / CuO / 24 h / Heating

7: 93 percent / lithium aluminium hydride / diethyl ether / 1) 0 deg C, 15 min, 2) r.t., 1 h

8: 93 percent / PBr₃, pyridine / CH₂Cl₂ / 24 h / Ambient temperature

With pyridine; manganese(IV) oxide; lithium aluminium tetrahydride; phosphorus tribromide; potassium carbonate; toluene-4-sulfonic acid; copper(II) oxide; In tetrahydrofuran; diethyl ether; dichloromethane; benzene;
DOI:10.1039/P19900001371

Reference yield:

: 74292-72-1
methyl 2-hydroxy-6-isopropoxybenzoate

: methyl 2-(2-formyl-3-isopropoxyphenoxy)-3-isopropoxy-5-methoxy-4-methylbenzoate

Guidance literature:: Multi-step reaction with 6 steps

1: 92 percent / lithium aluminium hydride / diethyl ether / 15 h / Ambient temperature

2: 83 percent / manganese dioxide / diethyl ether / 30 h / Ambient temperature

3: 71 percent / potassium carbonate / diethyl ether / 35 h

4: 68 percent / toluene p-sulphonic acid / benzene / 1 h / Heating

5: 73 percent / lithium aluminium hydride / tetrahydrofuran / 1 h / 0 °C

6: 26 percent / pyridine, potassium carbonate / CuO / 24 h / Heating

With pyridine; manganese(IV) oxide; lithium aluminium tetrahydride; potassium carbonate; toluene-4-sulfonic acid; copper(II) oxide; In tetrahydrofuran; diethyl ether; benzene;
DOI:10.1039/P19900001371