Butanedioic acid, 2,3-dihydroxy-2,3-dimethyl-

Base Information

• Chemical Name: Butanedioic acid, 2,3-dihydroxy-2,3-dimethyl-
• CAS No.: 74543-88-7
• Molecular Formula: C6H10O6
• European Community (EC) Number: 840-461-2
• DSSTox Substance ID: DTXSID90413589
• Nikkaji Number: J2.308.933E

Synonyms:74543-88-7;2,3-dihydroxy-2,3-dimethylbutanedioic acid;Butanedioic acid, 2,3-dihydroxy-2,3-dimethyl-;2,3-Dihydroxy-2,3-dimethylsuccinic acid;dimethyltartaric acid;SCHEMBL606619;DTXSID90413589;EN300-7437032;Z1262511826

Chemical Property of Butanedioic acid, 2,3-dihydroxy-2,3-dimethyl-

Chemical Property:

• XLogP3: -1.5
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 3
• Exact Mass: 178.04773803
• Heavy Atom Count: 12
• Complexity: 200

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(C(=O)O)(C(C)(C(=O)O)O)O

Technology Process of Butanedioic acid, 2,3-dihydroxy-2,3-dimethyl-

There total 2 articles about Butanedioic acid, 2,3-dihydroxy-2,3-dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-oxo-propionic acid (127-17-3) → LACTIC ACID (849585-22-4,106989-11-1,26811-96-1,31587-11-8,26100-51-6) + 2,3-dimethyltartaric acid (74543-88-7)

Guidance literature:

With ethanol; zinc;

Reference yield:

vanadium(II) perchlorate + 2-oxo-propionic acid (127-17-3) → 2,3-dimethyltartaric acid (74543-88-7) + vanadium(III) (22541-77-1)

Guidance literature:

With sodium perchlorate; In water; (Ar), V(2+) anf organic compound reacted at 26°C; mixture passed through column, to eluate added excess of BaCl2; UV; Kinetics;

DOI:10.1021/ja00529a028

Reference yield:

antimony(III) trioxide + (+/-)-dimethyltartaric acid (6863-95-2,14812-52-3,14812-53-4,34618-92-3,54809-00-6,74543-88-7) → 2Na(1+)*Sb2(C6H6O6)2(2-)*4H2O = Na2[Sb2(C6H6O6)2]*4H2O

Guidance literature:

With NaOH; In water; a slurry of Sb2O3, NaOH and (+/-)-dimethyltartaric acid in molar ratio of 1:2.2 heated for several days; filtered; pptd. by addn. of 95% ethanol to the warmed soln.; collected;washed with aqueous ethanol and acetone; air dried; elem. anal.;

DOI:10.1021/ja00538a002

upstream raw materials:

2-oxo-propionic acid

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