methyl 2,4-di-O-acetyl-3-deoxy-3-C-methyl-3-nitro-beta-D-xylopyranoside

Base Information

Chemical Name:methyl 2,4-di-O-acetyl-3-deoxy-3-C-methyl-3-nitro-beta-D-xylopyranoside
CAS No.:74595-62-3
Molecular Formula:C₁₁H₁₇NO₈
Molecular Weight:291.258
Hs Code.:
Mol file:74595-62-3.mol

Synonyms:methyl 2,4-di-O-acetyl-3-deoxy-3-C-methyl-3-nitro-beta-D-xylopyranoside

Suppliers and Price of methyl 2,4-di-O-acetyl-3-deoxy-3-C-methyl-3-nitro-beta-D-xylopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of methyl 2,4-di-O-acetyl-3-deoxy-3-C-methyl-3-nitro-beta-D-xylopyranoside

Chemical Property:

Vapor Pressure:7.75E-06mmHg at 25°C
Boiling Point:375.5°C at 760 mmHg
Flash Point:152.5°C
PSA：116.88000
Density:1.29g/cm³
LogP:0.41110

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of methyl 2,4-di-O-acetyl-3-deoxy-3-C-methyl-3-nitro-beta-D-xylopyranoside

There total 2 articles about methyl 2,4-di-O-acetyl-3-deoxy-3-C-methyl-3-nitro-beta-D-xylopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 79-24-3
Nitroethane

: 74584-39-7
(R)-2-methoxy-2,2'-oxy-bis-acetaldehyde

: 74584-40-0,74584-41-1,74584-42-2,74584-43-3,74595-62-3,75612-77-0
methyl 2,4-di-O-acetyl-3-deoxy-3-C-methyl-3-nitro-β-DL-arabinopyranoside

Guidance literature:: DOI:10.1016/S0008-6215(00)85563-9

Reference yield:

: 79-24-3
Nitroethane

: 74584-39-7
(R)-2-methoxy-2,2'-oxy-bis-acetaldehyde

: 108-24-7
acetic anhydride

: 74584-40-0
methyl 2,4-di-O-acetyl-3-deoxy-3-C-methyl-3-nitro-α-L-lyxopyranoside

: 74584-43-3
methyl 2,4-di-O-acetyl-3-deoxy-3-C-methyl-3-nitro-α-L-arabinopyranoside

: 74595-62-3
methyl 2,4-di-O-acetyl-3-deoxy-3-C-methyl-3-nitro-β-D-xylopyranoside

: 74584-41-1
methyl 2,4-di-O-acetyl-3-deoxy-3-C-methyl-3-nitro-β-D-arabinopyranoside

Guidance literature:: With pyridine; sodium ethanolate; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given; 1.) ethanol, room temperature, 4 h, 2.) 0 deg C, 1 h, room temperature, 24 h;

Reference yield:

: 74595-62-3
methyl 2,4-di-O-acetyl-3-deoxy-3-C-methyl-3-nitro-β-D-xylopyranoside

: 74584-54-6
methyl 3-acetamido-3-deoxy-3-C-methyl-4-O-toluene-p-sulphonyl-β-D-xylopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) hydrogen / 1.) Raney nickel / 1.) methanol, 30 atm, room temperature, 24 h, 2.) room temperature, 20 h

2: 28 percent / sodium hydroxide, tetrabutylammonium hydrogensulphate / H₂O; CH₂Cl₂ / 2 h / Ambient temperature

With sodium hydroxide; hydrogen; tetra(n-butyl)ammonium hydrogensulfate; nickel; In dichloromethane; water;