Bis(2-ethylhexyl)amine

Base Information

• Chemical Name: Bis(2-ethylhexyl)amine
• CAS No.: 106-20-7
• Deprecated CAS: 102095-26-1
• Molecular Formula: C16H35N
• Molecular Weight: 241.461
• Hs Code.: 2921.19
• European Community (EC) Number: 203-372-4,248-331-1
• NSC Number: 5329
• UN Number: 2735
• UNII: 9U5Q5UV6DB
• DSSTox Substance ID: DTXSID7025053
• Nikkaji Number: J27.961G
• Wikidata: Q26840939
• ChEMBL ID: CHEMBL1330355
• Mol file: 106-20-7.mol

Synonyms:Bis(2-ethylhexyl)amine;106-20-7;Di(2-ethylhexyl)amine;Diisooctylamine;1-Hexanamine, 2-ethyl-N-(2-ethylhexyl)-;Bis-2-ethylhexylamine;2,2'-Diethyldihexylamine;Diethylhexylamine;2-ethyl-N-(2-ethylhexyl)hexan-1-amine;2,2'-DIETHYLHEXYLAMINE;Di-(2-ethylhexyl)amine;Dihexylamine, 2,2'-diethyl-;NSC 5329;CCRIS 4619;EINECS 203-372-4;UNII-9U5Q5UV6DB;BRN 1748342;9U5Q5UV6DB;2-Ethyl-N-(2-ethylhexyl)-1-hexanamine;AI3-16574;27214-52-4;DTXSID7025053;NSC-5329;1-Hexylamine, 2-ethyl-N-(2-ethylhexyl)-;EC 203-372-4;2-Ethyl-N-(2-ethylhexyl)-hexan-1-amine;di-2-ethylhexylamine;Di(2-thylhexyl)amine;di-2-ethylhexyl amine;Bis(2-Ethylhexyl)amin;Di-(2-ethylhexyl)amin;22'-Diethyldihexylamine;bis(2-ethylhexyl) amine;di (2-etilhexil) amina;2,2'-Dietildihexilamina;Bis(2- ethylhexyl)amine;bis (2-etilhexil) amina;2 2'-Diethyldihexylamine;Dihexylamine,2'-diethyl-;di-(2-ethyl-hexyl)-amine;bis-(2-ethyl-hexyl)-amine;N N-Bis(2-ethylhexyl)amine;N,N-Bis(2-ethylhexyl)amine;Dihexilamina, 2,2'-dietil-;SCHEMBL123557;Bis(2-ethylhexyl)amine, 99%;DTXCID205053;DIETHYLHEXYLAMINE [INCI];CHEMBL1330355;N,N-Bis(2-ethylhexyl)amine #;SAIKULLUBZKPDA-UHFFFAOYSA-;N, N-bis (2-etilhexil) aminas;NSC5329;CHEBI:193588;AMY21861;EINECS 248-331-1;Tox21_200785;BBL011107;LS-394;MFCD00009489;STK802353;AKOS005622644;CS-W010280;Dihexylamine22'-diethyl-(6CI7CI8CI);NCGC00091719-01;NCGC00091719-02;NCGC00258339-01;1-Hexanamina, 2-etil-N-(2-etilhexil)-;CAS-106-20-7;VS-02838;WLN: 4Y2 & 1M1Y4 & 2;D0510;FT-0624575;Dihexylamine 2 2'-diethyl-(6CI 7CI 8CI);E75767;EN300-153163;Bis(2-ethylhexyl)amine, purum, >=98.0% (GC);W-108772;Q26840939;Z277467980

Chemical Property of Bis(2-ethylhexyl)amine

Chemical Property:

• Appearance/Colour: colourless liquid
• Vapor Pressure: 0.737mmHg at 25°C
• Melting Point: -60 °C
• Refractive Index: 1.4410 - 1.4440
• Boiling Point: 273.3 °C at 760 mmHg
• PKA: 40(at 25℃)
• Flash Point: 106.9 °C
• PSA: 12.03000
• Density: 0.798 g/cm³
• LogP: 5.39970
• Storage Temp.: Store below +30°C.
• Solubility.: 0.014g/l
• Water Solubility.: <0.2 g/L (20℃)
• XLogP3: 6.1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 12
• Exact Mass: 241.276950121
• Heavy Atom Count: 17
• Complexity: 129
• Transport DOT Label: Corrosive

Purity/Quality:

99% ^*data from raw suppliers

Bis(2-ethylhexyl) amine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C, Xi
• Hazard Codes: C:Corrosive
• Statements: R21/22:; R34:
• Safety Statements: S26:; S36:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Nitrogen Compounds -> Amines, Aliphatic
• Canonical SMILES: CCCCC(CC)CNCC(CC)CCCC
• Uses: Bis(2-ethylhexyl)amine (BEA) was used in the synthesis of stable nanosized CdS particles coated by an oriented monolayer of chemically bonded BEA molecules

Technology Process of Bis(2-ethylhexyl)amine

There total 10 articles about Bis(2-ethylhexyl)amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

2-Ethylhexylamine (104-75-6) → 2-ethyl-N-(2-ethylhexyl)-1-hexanamine (106-20-7)

Guidance literature:

With Co₂Rh₂/C; In toluene; at 180 ℃; for 18h; under 760.051 Torr; Autoclave; Inert atmosphere;

DOI:10.1002/adsc.201701522

Reference yield:

→ 2-ethyl-N-(2-ethylhexyl)-1-hexanamine (106-20-7) + rhodium (378784-00-0,7440-16-6)

Guidance literature:

Reference yield:

2-Ethylhexyl alcohol (104-76-7) → 2-Ethylhexylamine (104-75-6) + 2-ethyl-N-(2-ethylhexyl)-1-hexanamine (106-20-7)

Guidance literature:

With chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II); urea; diphenylphosphinopropane; In diethylene glycol dimethyl ether; at 160 ℃; for 12h; Autoclave; Inert atmosphere;

DOI:10.1080/00958972.2020.1804058

upstream raw materials:

(2-ethyl-hex-1-enyl)-(2-ethyl-hexyliden)-amine

2-ethylhexylidene 2-ethylhexyl amine

N,N-Di-(2-ethyl-hexyl)-N'-phenyl-harnstoff

N-methylaniline

Downstream raw materials:

3-(2,4-Dimethyl-phenyl)-1,1-bis-(2-ethyl-hexyl)-urea

N,N,N',N'-tetrakis(2-ethylhexyl)-5-iodoisophthalamide

bis(2-ethylhexyl)dimethylammonium 4-tert-butylphenolate

bis(2-ethylhexyl)dimethylammonium tosylate

Refernces

• 1、 Chung, Hyunho,Han, Seulgi,Chung, Young Keun,Park, Ji Hoon. "Conversion of Primary Amines to Symmetrical Secondary and Tertiary Amines using a Co-Rh Heterobimetallic Nanocatalyst". supporting information. p. 1267 - 1272. Retrieved 2018/02/12.
• 2、 -. "Bis(dibenzoxazoyl)thiophene fluorescent brighteners". . . Retrieved 2008/06/13.