3-Bromoquinolizinium bromide

Base Information

Chemical Name:3-Bromoquinolizinium bromide
CAS No.:77199-12-3
Molecular Formula:C9H7BrN.Br
Molecular Weight:288.969
Hs Code.:
DSSTox Substance ID:DTXSID70463128
Mol file:77199-12-3.mol

Synonyms:3-Bromoquinolizinium bromide;77199-12-3;3-bromoquinolizin-5-ium;bromide;DTXSID70463128;FT-0711063

Suppliers and Price of 3-Bromoquinolizinium bromide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 3-Bromoquinolizinium bromide

Chemical Property:

PSA：4.10000
LogP:-0.80820
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:288.89247
Heavy Atom Count:12
Complexity:138

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC=[N+]2C=C(C=CC2=C1)Br.[Br-]

Technology Process of 3-Bromoquinolizinium bromide

There total 6 articles about 3-Bromoquinolizinium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 7-bromo-1-oxo-1,2,3,4-tetrahydroquinolizinium bromide

: 77199-12-3
3-bromo-quinolizinium bromide

Guidance literature:: With acetic anhydride;

Reference yield:

: 3,4-dihydro-2-cyano-7-bromo-quinolizinium-1-olate

: 77199-12-3
3-bromo-quinolizinium bromide

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / HBr / H₂O / 24 h / 120 °C

2: Ac₂O

With hydrogen bromide; acetic anhydride; In water;
DOI:10.1021/jo060634+

Reference yield:

: 3430-13-5
5-bromo-2-methylpyridine

: 77199-12-3
3-bromo-quinolizinium bromide

Guidance literature:: Multi-step reaction with 5 steps

1: KMnO₄, H₂O / 6 h / 100 °C

2: 1.) SOCl₂ / 1.) reflux, 2 h, 2.) toluene, reflux, 2 h

3: 47 percent / NaH / toluene

4: aq. 47percent HBr / 0.33 h / Heating

5: 67 percent / acetic anhydride

With potassium permanganate; thionyl chloride; water; hydrogen bromide; acetic anhydride; sodium hydride; In toluene;