Methanone, (1-cyclohexyl-2,3-aziridinediyl)bis[phenyl-, cis-

Base Information

• Chemical Name: Methanone, (1-cyclohexyl-2,3-aziridinediyl)bis[phenyl-, cis-
• CAS No.: 802-60-8
• Molecular Formula: C₂₂H₂₃NO₂
• Molecular Weight: 333.43

Synonyms:

Chemical Property of Methanone, (1-cyclohexyl-2,3-aziridinediyl)bis[phenyl-, cis-

Chemical Property:

Purity/Quality:

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MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methanone, (1-cyclohexyl-2,3-aziridinediyl)bis[phenyl-, cis-

There total 2 articles about Methanone, (1-cyclohexyl-2,3-aziridinediyl)bis[phenyl-, cis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ trans-N-Cyclohexyl-2,3-dibenzoyl-aziridin (802-60-8,802-61-9,95130-32-8)

Guidance literature:

meso-1,2-Dibenzoyl-1,2-dibrom-ethan, 1) Bzl. Δ, 2) Cyclohexylamin (3 Mol), 40grad;

DOI:10.1021/ja01083a020

Reference yield:

→ cis-1-cyclohexyl-2,3-dibenzoylaziridine (802-60-8)

Guidance literature:

trans-1-Cyclohexyl-2,3-dibenzoyl-aziridin, ethanol. Natriumethylatlsg., Δ;

DOI:10.1021/ja01083a020

Reference yield: 52.0%

trans-1-cyclohexyl-2,3-dibenzoylaziridine (802-60-8,802-61-9,95130-32-8) → (Z)-2-(cyclohexylamino)-1,4-diphenylbut-2-ene-1,4-dione

Guidance literature:

In benzene; at 25 ℃; for 4h; Irradiation;

DOI:10.1021/jo952047m

Downstream raw materials:

3-cyclohexyl-1,5-diphenyl-(1rO,2tH,4tH,5cO)-9-oxa-3-aza-tricyclo[3.3.1.0^2,4]nonan-7-one

dimethyl meso-2,3-dibenzoylsuccinate

2-Benzoyl-1-cyclohexyl-1H-pyrrole-3,4-dicarboxylic acid dimethyl ester

12-Hydroxy-12-phenyl-1-aza-dispiro[4.0.5.1]dodeca-1,3-diene-3,4-dicarboxylic acid dimethyl ester

Refernces

10.1021/ja01522a036

The research explores the oxidation of unsymmetrically substituted 1,1-dibenzylhydrazines using various oxidizing agents to produce unsymmetrical bibenzyls. The study aims to delineate the scope and limitations of these oxidation reactions and to understand the mechanism behind the formation of bibenzyls. Key chemicals used include 1,1-dibenzylhydrazines with substituents such as methoxy, methyl, chlorine, and furyl groups, and oxidizing agents like yellow mercuric oxide, potassium permanganate, quinone, mercuric acetate, and Fehling solution. The researchers found that the oxidation with yellow mercuric oxide consistently produced the desired bibenzyls, while other oxidizing agents led to different products, such as tetrazenes. The study concludes that the nature of the substituents and the choice of oxidizing agent significantly influence the outcome of the oxidation reactions. The findings suggest that the oxidation process involves an intermediate state where the terminal nitrogen lacks hydrogens, leading to the loss of nitrogen and coupling of the benzyl residues to form bibenzyls. The research also highlights the potential of alkaline decomposition of benzenesulfonyl derivatives of these hydrazines as an alternative method to produce bibenzyls with better yields and purity.

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