Hexanal, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-[2-[[(1,1-dimethylethyl)dimethyl silyl]oxy]ethylidene]-6-[(4-methoxyphenyl)methoxy]-, (3E,5R)-

Base Information

Chemical Name:Hexanal, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-[2-[[(1,1-dimethylethyl)dimethyl silyl]oxy]ethylidene]-6-[(4-methoxyphenyl)methoxy]-, (3E,5R)-
CAS No.:807364-12-1
Molecular Formula:C28H50O5Si2
Molecular Weight:522.873
Hs Code.:

Hexanal,
5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-[2-[[(1,1-dimethylethyl)dimethyl
silyl]oxy]ethylidene]-6-[(4-methoxyphenyl)methoxy]-, (3E,5R)-

Synonyms:

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Chemical Property of Hexanal, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-[2-[[(1,1-dimethylethyl)dimethyl silyl]oxy]ethylidene]-6-[(4-methoxyphenyl)methoxy]-, (3E,5R)-

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Technology Process of Hexanal, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-[2-[[(1,1-dimethylethyl)dimethyl silyl]oxy]ethylidene]-6-[(4-methoxyphenyl)methoxy]-, (3E,5R)-

There total 6 articles about Hexanal, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-[2-[[(1,1-dimethylethyl)dimethyl silyl]oxy]ethylidene]-6-[(4-methoxyphenyl)methoxy]-, (3E,5R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: (Z,2RS,6R)-6-tert-butyldimethylsilyloxy-4-(2-tert-butyldimethylsilyloxyethylidene)-7-(4-methoxybenzyloxy)heptane-1,2-diol

: 807364-12-1
(E,5R)-5-tert-butyldimethylsilyloxy-3-(2-tert-butyldimethylsilyloxyethylidene)-6-(4-methoxybenzyloxy)hexanal

Guidance literature:: With sodium periodate; In methanol;
DOI:10.1016/j.tetlet.2004.09.124

Reference yield:

: 214914-80-4
methyl (5R)-5-hydroxy-6-(4-methoxybenzyloxy)hex-2-ynoate

: 807364-12-1
(E,5R)-5-tert-butyldimethylsilyloxy-3-(2-tert-butyldimethylsilyloxyethylidene)-6-(4-methoxybenzyloxy)hexanal

Guidance literature:: Multi-step reaction with 5 steps

1: LiCl / CuCl / -78 °C

2: DIBAL-H / tetrahydrofuran

3: 2,6-lutidine / tetrahydrofuran

4: 70 percent / ADmix β; OsO4 / butan-1-ol; H2O

5: 100 percent / NaIO₄ / methanol

With 2,6-dimethylpyridine; sodium periodate; osmium(VIII) oxide; diisobutylaluminium hydride; 1,4-bis(9-O-dihydroquinidine)phthalazine; lithium chloride; copper(l) chloride; In tetrahydrofuran; methanol; water; butan-1-ol;
DOI:10.1016/j.tetlet.2004.09.124

Reference yield:

: 807363-99-1
methyl (2Z,5R)-5-hydroxy-6-(4-methoxybenzyloxy)-3-prop-2-enylhex-2-enoate

: 807364-12-1
(E,5R)-5-tert-butyldimethylsilyloxy-3-(2-tert-butyldimethylsilyloxyethylidene)-6-(4-methoxybenzyloxy)hexanal

Guidance literature:: Multi-step reaction with 4 steps

1: DIBAL-H / tetrahydrofuran

2: 2,6-lutidine / tetrahydrofuran

3: 70 percent / ADmix β; OsO4 / butan-1-ol; H2O

4: 100 percent / NaIO₄ / methanol

With 2,6-dimethylpyridine; sodium periodate; osmium(VIII) oxide; diisobutylaluminium hydride; 1,4-bis(9-O-dihydroquinidine)phthalazine; In tetrahydrofuran; methanol; water; butan-1-ol;
DOI:10.1016/j.tetlet.2004.09.124