5,6-Di(benzenesulfonyl)bicyclo[2.2.2]oct-2-ene

Base Information

Chemical Name:5,6-Di(benzenesulfonyl)bicyclo[2.2.2]oct-2-ene
CAS No.:807627-79-8
Molecular Formula:C₂₀H₂₀O₄S₂
Molecular Weight:388.508
Hs Code.:
DSSTox Substance ID:DTXSID20509626

Synonyms:807627-79-8;5,6-Di(benzenesulfonyl)bicyclo[2.2.2]oct-2-ene;SCHEMBL2000854;DTXSID20509626;CVIZSRYBTFXZDT-UHFFFAOYSA-N;5, 6-diphenylsulfonyl-bicyclo-[2,2,2]oct-2-ene;5,6-diphenylsulfonyl-bicyclo-[2,2,2]oct-2-ene;5,6-bis(phenylsulfonyl)-bicyclo[2,2,2]octa-2-ene;5,6-bis(phenylsulfonyl)-bicyclo[2.2.2]octa-2-ene

Suppliers and Price of 5,6-Di(benzenesulfonyl)bicyclo[2.2.2]oct-2-ene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of 5,6-Di(benzenesulfonyl)bicyclo[2.2.2]oct-2-ene

Chemical Property:

XLogP3:3.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:388.08030146
Heavy Atom Count:26
Complexity:666

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC2C=CC1C(C2S(=O)(=O)C3=CC=CC=C3)S(=O)(=O)C4=CC=CC=C4

Technology Process of 5,6-Di(benzenesulfonyl)bicyclo[2.2.2]oct-2-ene

There total 4 articles about 5,6-Di(benzenesulfonyl)bicyclo[2.2.2]oct-2-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 963-16-6
(E)-1,2-bis(phenylsulfonyl)ethylene

: 1165952-91-9
cyclohexa-1,3-diene

: 807627-79-8
2,3-bis(phenylsulfonyl)bicyclo[2.2.2]oct-5-ene

Guidance literature:: In toluene; for 20h; Heating;
DOI:10.3987/COM-05-S(T)23

Reference yield:

: 23528-44-1
1,2-bis-(phenylmercapto)ethylene

: 807627-79-8
2,3-bis(phenylsulfonyl)bicyclo[2.2.2]oct-5-ene

Guidance literature:: Multi-step reaction with 2 steps

1: 2-Thiobarbituric acid; sodium tungstate; dihydrogen peroxide; phenylphosphonate / 1,2-dichloro-ethane

2: toluene / 120 °C

With sodium tungstate; phenylphosphonate; dihydrogen peroxide; 2-Thiobarbituric acid; In 1,2-dichloro-ethane; toluene;
DOI:10.1002/anie.202016674

Reference yield:

: 108-98-5
thiophenol

: 807627-79-8
2,3-bis(phenylsulfonyl)bicyclo[2.2.2]oct-5-ene

Guidance literature:: Multi-step reaction with 3 steps

1: potassium hydroxide / ethanol / 22 h / 90 °C

2: 2-Thiobarbituric acid; sodium tungstate; dihydrogen peroxide; phenylphosphonate / 1,2-dichloro-ethane

3: toluene / 120 °C

With sodium tungstate; phenylphosphonate; dihydrogen peroxide; 2-Thiobarbituric acid; potassium hydroxide; In ethanol; 1,2-dichloro-ethane; toluene;
DOI:10.1002/anie.202016674