(2S)-2-methylpentanal

Base Information

Chemical Name:(2S)-2-methylpentanal
CAS No.:82043-22-9
Molecular Formula:C6H12O
Molecular Weight:100.161
Hs Code.:
DSSTox Substance ID:DTXSID60426429
Nikkaji Number:J1.662.678C
Wikidata:Q82239348

Synonyms:(2S)-2-methylpentanal;82043-22-9;(s)-2-methylpentanal;SCHEMBL1939674;DTXSID60426429

Suppliers and Price of (2S)-2-methylpentanal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of (2S)-2-methylpentanal

Chemical Property:

XLogP3:1.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:100.088815002
Heavy Atom Count:7
Complexity:50.1

Purity/Quality:: 99.3% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCC(C)C=O
Isomeric SMILES:CCC[C@H](C)C=O

Technology Process of (2S)-2-methylpentanal

There total 2 articles about (2S)-2-methylpentanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 59983-39-0,187035-29-6
(S)-1-amino-2-(methoxymethyl)pyrrolidine

: 82043-22-9
(S)-(-)-2-methylpentanal

Guidance literature:: Multi-step reaction with 3 steps

1.1: 98 percent / CH₂Cl₂ / 20 h / 20 °C

2.1: 2,2,6,6-tetramethylpiperidine; n-BuLi / tetrahydrofuran; hexane / 2 h / 0 °C

2.2: tetrahydrofuran; hexane / 20 h / -78 - 20 °C

3.1: ag. HCl / pentane / 0.25 h / 20 °C

With 2,2,6,6-tetramethyl-piperidine; hydrogenchloride; n-butyllithium; In tetrahydrofuran; hexane; dichloromethane; pentane;
DOI:10.1039/b006832m

Reference yield:

: 72748-99-3,187035-29-6
(R)-1-Amino-2-(methoxymethyl)pyrrolidine

: 82043-22-9
(S)-(-)-2-methylpentanal

Guidance literature:: Multi-step reaction with 3 steps

1.1: 95 percent / CH₂Cl₂ / 20 h / 20 °C

2.1: 2,2,6,6-tetramethylpiperidine; n-BuLi / tetrahydrofuran; hexane / 2 h / 0 °C

2.2: tetrahydrofuran; hexane / 20 h / -78 - 20 °C

3.1: ag. HCl / pentane / 0.25 h / 20 °C

With 2,2,6,6-tetramethyl-piperidine; hydrogenchloride; n-butyllithium; In tetrahydrofuran; hexane; dichloromethane; pentane;
DOI:10.1039/b006832m

Reference yield: 80.0%

: 4-(benzyloxy)-1-((3aR,6S,7aS)-8,8-dimethyl-2,2-dioxidohexahydro-1H-3a,6-methanobenzo[c]isothiazol-1-yl)butan-1-one

: 82043-22-9
(S)-(-)-2-methylpentanal

: C₂₇H₄₁NO₅S

Guidance literature:: 4-(benzyloxy)-1-((3aR,6S,7aS)-8,8-dimethyl-2,2-dioxidohexahydro-1H-3a,6-methanobenzo[c]isothiazol-1-yl)butan-1-one; With t-butyldimethylsiyl triflate; triethylamine; In dichloromethane; at 20 ℃;

(S)-(-)-2-methylpentanal; With titanium tetrachloride; In dichloromethane; at -78 ℃; for 3h; diastereoselective reaction;
DOI:10.1021/acs.jnatprod.5b01143