Sodium 1,2,3,4,5-pentaphenylcyclopenta-2,4-dien-1-ide

Base Information

Chemical Name:Sodium 1,2,3,4,5-pentaphenylcyclopenta-2,4-dien-1-ide
CAS No.:82207-56-5
Molecular Formula:C35H25Na
Molecular Weight:468.573
Hs Code.:
DSSTox Substance ID:DTXSID90556642

Synonyms:82207-56-5;DTXSID90556642;Sodium 1,2,3,4,5-pentaphenylcyclopenta-2,4-dien-1-ide

Suppliers and Price of Sodium 1,2,3,4,5-pentaphenylcyclopenta-2,4-dien-1-ide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of Sodium 1,2,3,4,5-pentaphenylcyclopenta-2,4-dien-1-ide

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:4
Exact Mass:468.18539508
Heavy Atom Count:36
Complexity:567

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC=C(C=C1)[C-]2C(=C(C(=C2C3=CC=CC=C3)C4=CC=CC=C4)C5=CC=CC=C5)C6=CC=CC=C6.[Na+]

Technology Process of Sodium 1,2,3,4,5-pentaphenylcyclopenta-2,4-dien-1-ide

There total 1 articles about Sodium 1,2,3,4,5-pentaphenylcyclopenta-2,4-dien-1-ide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 2519-10-0
1,2,3,4,5-pentaphenylcyclopentadiene

: 82207-56-5
sodium pentaphenylcyclopentadienide

Guidance literature:: With sodium; In toluene; at 110 ℃;
DOI:10.1016/S0022-328X(00)90273-0

Reference yield: 56.0%

: 60349-53-3
tetrakis[chloro(triethylphosphine)silver(I)]

: 82207-56-5
sodium pentaphenylcyclopentadienide

: 303767-99-9
(η-pentaphenylcyclopentadienyl)(triethylphosphine)silver(I)

Guidance literature:: In tetrahydrofuran; under Ar; the mixt. of Na(C5(C6H5)5) and the Ag complex was cooled to -78°C, THF was added, the mixt. was stirred for 3 h at -78°C, gradually warmed to 0°C; the solvent was evapd. in vac., the residue was extd. with (C2H5)2O, the soln. was allowed to cryst. at -20°C; elem. anal.;
DOI:10.1021/om000618h

Reference yield: 44.0%

: chloro(triethylphosphine)copper tetramer

: 82207-56-5
sodium pentaphenylcyclopentadienide

: 303768-00-5
(η-pentaphenylcyclopentadienyl)(triethylphosphine)copper(I)

Guidance literature:: In tetrahydrofuran; under Ar; the mixt. of Na(C5(C6H5)5) and the Cu complex was cooled to -10°C, THF was added, the mixt. was stirred for 2 h at -10°C, gradually warmed to 25°C, stirred for 2 h; the solvent was evapd. in vac., the residue was extd. with (C2H5)2O, the soln. was filtered through Celite and allowed to cryst. at -20°C; elem. anal.;
DOI:10.1021/om000618h