Phosphine, diphenyl[(phenylthio)methyl]-

Base Information

Chemical Name:Phosphine, diphenyl[(phenylthio)methyl]-
CAS No.:82270-61-9
Molecular Formula:C19H17PS
Molecular Weight:308.384
Hs Code.:
DSSTox Substance ID:DTXSID20423212
Nikkaji Number:J1.032.984A
Wikidata:Q82235366

Synonyms:Phosphine, diphenyl[(phenylthio)methyl]-;82270-61-9;DTXSID20423212;diphenyl(phenylthiomethyl)phosphine

Suppliers and Price of Phosphine, diphenyl[(phenylthio)methyl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Phosphine, diphenyl[(phenylthio)methyl]-

Chemical Property:

XLogP3:5.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:5
Exact Mass:308.07885871
Heavy Atom Count:21
Complexity:257

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(CSC2=CC=CC=C2)C3=CC=CC=C3

Technology Process of Phosphine, diphenyl[(phenylthio)methyl]-

There total 5 articles about Phosphine, diphenyl[(phenylthio)methyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 7205-91-6
phenylthiomethyl chloride

: 15475-27-1,4346-39-8
potassium diphenylphosphine

: 82270-61-9
(diphenylphosphanyl)(thiophenyl)methane

Guidance literature:: In tetrahydrofuran; 1.) rt, overnight; 2.) reflux, 4 h;

Reference yield:

: 14044-65-6
borane-THF

: 31238-57-0
diphenyl(phenylthiomethyl)phosphine oxide

: diphenyl(phenylthiomethyl)phosphine-borane

: 82270-61-9
(diphenylphosphanyl)(thiophenyl)methane

Guidance literature:: With titanium(IV) isopropylate; In tetrahydrofuran; toluene; at 80 ℃; for 24h; Schlenk technique; Inert atmosphere;
DOI:10.1016/j.tet.2021.132057

Reference yield:

: (diphenylphosphoryl)methyl mesylate

: diphenyl(phenylthiomethyl)phosphine-borane

: 82270-61-9
(diphenylphosphanyl)(thiophenyl)methane

Guidance literature:: Multi-step reaction with 2 steps

1: n-butyllithium / tetrahydrofuran / 72 h / -78 - 20 °C

2: titanium(IV) isopropylate / toluene; tetrahydrofuran / 24 h / 80 °C / Schlenk technique; Inert atmosphere

With titanium(IV) isopropylate; n-butyllithium; In tetrahydrofuran; toluene;
DOI:10.1016/j.tet.2021.132057