CID 11490323

Base Information

Chemical Name:CID 11490323
CAS No.:835624-47-0
Molecular Formula:C16H10BrF15O2
Molecular Weight:599.134
Hs Code.:
DSSTox Substance ID:DTXSID601023049
Nikkaji Number:J2.130.991E

Synonyms:DTXSID601023049;835624-47-0;1-bromo-2-[(1R)-2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-(methoxymethoxy)octyl]benzene

Suppliers and Price of CID 11490323

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 0 raw suppliers

Chemical Property of CID 11490323

Chemical Property:

XLogP3:7.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:17
Rotatable Bond Count:10
Exact Mass:597.96246
Heavy Atom Count:34
Complexity:694

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COCOC(C1=CC=CC=C1Br)C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F
Isomeric SMILES:COCO[C@H](C1=CC=CC=C1Br)C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F

Technology Process of CID 11490323

There total 4 articles about CID 11490323 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 107-30-2
chloromethyl methyl ether

: 835624-45-8
(R)-1-bromo-2-(1-hydroxy-1H-perfluorooctyl)benzene

: 835624-47-0
(R)-1-bromo-2-(1-methoxymethoxy-1H-perfluorooctyl)benzene

Guidance literature:: With sodium hydride; In tetrahydrofuran;
DOI:10.1016/j.tetlet.2004.11.038

Reference yield:

: 3108-24-5
ethyl perfluorooctanoate

: 835624-47-0
(R)-1-bromo-2-(1-methoxymethoxy-1H-perfluorooctyl)benzene

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / hexane; tetrahydrofuran; diethyl ether / 0.33 h / -110 °C

1.2: 84 percent / hexane; tetrahydrofuran; diethyl ether / 1 h / -110 °C

2.1: 96 percent / catecholborane; (R)-2-methyl-5,5-diphenyl-3,4-propano-1,3,2-oxazaborolidine / tetrahydrofuran / -78 - -30 °C

3.1: 92 percent / sodium hydride / tetrahydrofuran; various solvent(s) / 20 °C

With n-butyllithium; sodium hydride; (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole; benzo[1,3,2]dioxaborole; In tetrahydrofuran; diethyl ether; hexane;
DOI:10.1016/j.tet.2005.11.063

Reference yield:

: 583-53-9
2,3-dibromobenzene

: 835624-47-0
(R)-1-bromo-2-(1-methoxymethoxy-1H-perfluorooctyl)benzene

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / hexane; tetrahydrofuran; diethyl ether / 0.33 h / -110 °C

1.2: 84 percent / hexane; tetrahydrofuran; diethyl ether / 1 h / -110 °C

2.1: 96 percent / catecholborane; (R)-2-methyl-5,5-diphenyl-3,4-propano-1,3,2-oxazaborolidine / tetrahydrofuran / -78 - -30 °C

3.1: 92 percent / sodium hydride / tetrahydrofuran; various solvent(s) / 20 °C

With n-butyllithium; sodium hydride; (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole; benzo[1,3,2]dioxaborole; In tetrahydrofuran; diethyl ether; hexane;
DOI:10.1016/j.tet.2005.11.063