Diphenyliodonium iodide

Base Information

• Chemical Name: Diphenyliodonium iodide
• CAS No.: 2217-79-0
• Molecular Formula: C12H10 I . I
• Molecular Weight: 408.02
• Hs Code.: 29319090
• European Community (EC) Number: 218-716-9
• DSSTox Substance ID: DTXSID10944820
• Mol file: 2217-79-0.mol

Synonyms:diphenyliodonium;diphenyliodonium bromide;diphenyliodonium chloride;diphenyliodonium hexafluoroarsenate;diphenyliodonium hexafluorophosphate;diphenyliodonium iodide;diphenyliodonium nitrate;diphenyliodonium nitrite;diphenyliodonium sulfate (1:1);diphenyliodonium tosylate;iodonium biphenyl;iodoniumdiphenyl

Chemical Property of Diphenyliodonium iodide

Chemical Property:

• Melting Point: 162-164°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: -3.18100
• Sensitive.: Light Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 407.88720
• Heavy Atom Count: 14
• Complexity: 116

Purity/Quality:

97% ^*data from raw suppliers

Diphenyliodonium Iodide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R36/37/38:Irritating to eyes, respiratory system and skin.
• Hazard Codes: Xi
• Statements: 36/37/38-25
• Safety Statements: 26-36/37/39-37/39-45-36/37

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[I+]C2=CC=CC=C2.[I-]
• Uses: Diphenyliodonium Iodide is used as a catalyst in radical polymerizations.

Technology Process of Diphenyliodonium iodide

There total 8 articles about Diphenyliodonium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

iodobenzene (591-50-4) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → diphenyliodonium iodide (2217-79-0)

Guidance literature:

at 50 ℃; for 1.5h;

DOI:10.1246/bcsj.70.219

Reference yield: 44.0%

benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → iodobenzene (591-50-4) + diphenyliodonium iodide (2217-79-0)

Guidance literature:

With chromium(VI) oxide; sulfuric acid; iodine; In acetic anhydride; acetic acid; at 20 - 45 ℃;

DOI:10.1246/bcsj.70.1665

Reference yield:

phenyllithium (591-51-5) → diphenyliodonium iodide (2217-79-0)

Guidance literature:

With iodine trichloride;

DOI:10.1021/ja01496a066

upstream raw materials:

(Dichloroiodo)benzene

trans-chlorovinyliodonium dichloride

phenyllithium

benzene

Downstream raw materials:

iodobenzene

5,7-dihydro-2-methyl-7-phenylpyrimido<5,4-d>benzazepin-6(6H)-one

8-chloro-1-phenyl-4-<(dimethylamino)methylidene>-3,4-dihydro-1H-1-benzazepine-2,5-dione

10-chloro-5,7-dihydro-2-methyl-7-phenylpyrimido<5,4-d>benzazepin-6(6H)-one