4-Cyclohexenyl radical

Base Information

• Chemical Name: 4-Cyclohexenyl radical
• CAS No.: 15650-80-3
• Molecular Formula: C₆H₉
• Molecular Weight: 81.1375
• Nikkaji Number: J1.786.958B
• Mol file: 15650-80-3.mol

Synonyms:4-Cyclohexenyl radical;15650-80-3

Chemical Property of 4-Cyclohexenyl radical

Chemical Property:

• Boiling Point: 85.6°Cat760mmHg
• Flash Point: °C
• Density: 0.823g/cm³
• XLogP3: 2.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 81.070425287
• Heavy Atom Count: 6
• Complexity: 53.1

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1CC=CC[CH]1

Technology Process of 4-Cyclohexenyl radical

There total 7 articles about 4-Cyclohexenyl radical which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cyclohexane-1,2-epoxide (286-20-4) → 3-Cyclohexenyl cation (7493-04-1,15650-80-3,20693-99-6,38132-10-4,60690-49-5,125081-53-0)

Guidance literature:

In fluorosulphonic acid; at -30 ℃; for 120h; Yield given;

Reference yield:

4-Iodocyclohexene (2566-56-5) → cyclohex-3-enyl (15650-80-3,1254592-05-6)

Guidance literature:

With di-tert-butyl peroxide; hexamethyldistannane; Irradiation;

DOI:10.1021/jo00391a026

Reference yield:

cyclohexa-1,4-diene (1165952-92-0) → cyclohex-3-enyl (15650-80-3,1254592-05-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.22 g / KI, 85percent phosphoric acid / 16 h / 85 °C

2: di-tert-butyl peroxide, hexamethyldistannane / Irradiation

With di-tert-butyl peroxide; phosphoric acid; hexamethyldistannane; potassium iodide;

DOI:10.1021/jo00391a026

upstream raw materials:

Bicyclo<3.1.0>hexan-2-ol

cyclohexane-1,2-epoxide

allyl bromide

4-Iodocyclohexene