4H-1,3-Benzodioxin-4-one, 7-hydroxy-5-(2-oxoheptyl)-2,2-diphenyl-

Base Information

Chemical Name:4H-1,3-Benzodioxin-4-one, 7-hydroxy-5-(2-oxoheptyl)-2,2-diphenyl-
CAS No.:846607-03-2
Molecular Formula:C27H26O5
Molecular Weight:430.5
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 4H-1,3-Benzodioxin-4-one, 7-hydroxy-5-(2-oxoheptyl)-2,2-diphenyl-

Chemical Property:

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Technology Process of 4H-1,3-Benzodioxin-4-one, 7-hydroxy-5-(2-oxoheptyl)-2,2-diphenyl-

There total 11 articles about 4H-1,3-Benzodioxin-4-one, 7-hydroxy-5-(2-oxoheptyl)-2,2-diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 846606-85-7
7-benzyloxy-5-(2-oxoheptyl)-2,2-diphenylbenzo[1,3]dioxin-4-one

: 846607-03-2
7-hydroxy-5-(2-oxoheptyl)-2,2-diphenylbenzo[1,3]dioxin-4-one

Guidance literature:: With hydrogen; palladium on activated charcoal; In ethyl acetate; at 20 ℃; for 5h; balloon pressure;
DOI:10.1021/ol047507p

Reference yield:

: 846607-01-0
5,7-dihydroxy-2,2-diphenylbenzo[1,3]dioxin-4-one

: 846607-03-2
7-hydroxy-5-(2-oxoheptyl)-2,2-diphenylbenzo[1,3]dioxin-4-one

Guidance literature:: Multi-step reaction with 6 steps

1: 75 percent / triphenylphosphine; DIAD / tetrahydrofuran / 2 h / 0 - 20 °C

2: 94 percent / pyridine / CH₂Cl₂ / 1.5 h / 20 °C

3: 80 percent / tBuNH₂ / PdCl₂(dppf)*CH₂Cl₂ / propan-2-ol; H₂O / Heating

4: 79 percent / m-CPBA / CH₂Cl₂; H₂O / 3 h / 20 °C / pH 7

5: 84 percent / tributylphosphine / Pd(OAc)2 / 2-methyl-propan-2-ol / 4 h / Heating

6: 90 percent / H₂ / Pd/C / ethyl acetate / 5 h / 20 °C / balloon pressure

With pyridine; tributylphosphine; di-isopropyl azodicarboxylate; hydrogen; tert-butylamine; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; palladium diacetate; palladium on activated charcoal; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; In tetrahydrofuran; dichloromethane; water; ethyl acetate; isopropyl alcohol; tert-butyl alcohol;
DOI:10.1021/ol047507p

Reference yield:

: 846607-02-1
7-(benzyloxy)-5-hydroxy-2,2-diphenyl-4H-benzo[d][1,3]dioxin-4-one

: 846607-03-2
7-hydroxy-5-(2-oxoheptyl)-2,2-diphenylbenzo[1,3]dioxin-4-one

Guidance literature:: Multi-step reaction with 5 steps

1: 94 percent / pyridine / CH₂Cl₂ / 1.5 h / 20 °C

2: 80 percent / tBuNH₂ / PdCl₂(dppf)*CH₂Cl₂ / propan-2-ol; H₂O / Heating

3: 79 percent / m-CPBA / CH₂Cl₂; H₂O / 3 h / 20 °C / pH 7

4: 84 percent / tributylphosphine / Pd(OAc)2 / 2-methyl-propan-2-ol / 4 h / Heating

5: 90 percent / H₂ / Pd/C / ethyl acetate / 5 h / 20 °C / balloon pressure

With pyridine; tributylphosphine; hydrogen; tert-butylamine; 3-chloro-benzenecarboperoxoic acid; palladium diacetate; palladium on activated charcoal; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; In dichloromethane; water; ethyl acetate; isopropyl alcohol; tert-butyl alcohol;
DOI:10.1021/ol047507p