Technology Process of Naphthalene, 1,2-dihydro-4-methyl-7-[2-[4-(2-methylpropyl)phenyl]ethyl]-
There total 5 articles about Naphthalene, 1,2-dihydro-4-methyl-7-[2-[4-(2-methylpropyl)phenyl]ethyl]- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
toluene-4-sulfonic acid;
In
dichloromethane;
at 20 ℃;
for 2h;
- Guidance literature:
-
Multi-step reaction with 5 steps
1: triethylamine / dichloromethane / 1 h / -78 - 0 °C
2: copper(l) iodide; triethylamine / tetrakis(triphenylphosphine) palladium(0) / N,N-dimethyl-formamide / 19.08 h / 20 °C
3: tetrahydrofuran; diethyl ether / 0.5 h / 0 °C
4: hydrogen / palladium 10% on activated carbon / ethanol / 0.25 h
5: toluene-4-sulfonic acid / dichloromethane / 2 h / 20 °C
With
copper(l) iodide; hydrogen; toluene-4-sulfonic acid; triethylamine;
tetrakis(triphenylphosphine) palladium(0); palladium 10% on activated carbon;
In
tetrahydrofuran; diethyl ether; ethanol; dichloromethane; N,N-dimethyl-formamide;
- Guidance literature:
-
Multi-step reaction with 3 steps
1: tetrahydrofuran; diethyl ether / 0.5 h / 0 °C
2: hydrogen / palladium 10% on activated carbon / ethanol / 0.25 h
3: toluene-4-sulfonic acid / dichloromethane / 2 h / 20 °C
With
hydrogen; toluene-4-sulfonic acid;
palladium 10% on activated carbon;
In
tetrahydrofuran; diethyl ether; ethanol; dichloromethane;