Dehydropipernonaline

Base Information

Chemical Name:Dehydropipernonaline
CAS No.:107584-38-3
Molecular Formula:C₂₁H₂₅NO₃
Molecular Weight:339.434
Hs Code.:2934999090
DSSTox Substance ID:DTXSID401315333
Nikkaji Number:J2.471.186B
Wikidata:Q76386734
Metabolomics Workbench ID:49170
ChEMBL ID:CHEMBL483708
Mol file:107584-38-3.mol

Synonyms:dehydropipernonaline;N-(9-(3,4-methylenedioxyphenyl)-2,4,8-nonatrienoyl)piperidine

Suppliers and Price of Dehydropipernonaline

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of Dehydropipernonaline

Chemical Property:

Vapor Pressure:1.52E-13mmHg at 25°C
Boiling Point:582.2°Cat760mmHg
Flash Point:305.9°C
PSA：38.77000
Density:1.15g/cm³
LogP:4.27150
XLogP3:4.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:6
Exact Mass:339.18344366
Heavy Atom Count:25
Complexity:505

Purity/Quality:: 1%-101.0% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CCN(CC1)C(=O)C=CC=CCCC=CC2=CC3=C(C=C2)OCO3
Isomeric SMILES:C1CCN(CC1)C(=O)/C=C/C=C/CC/C=C/C2=CC3=C(C=C2)OCO3

Technology Process of Dehydropipernonaline

There total 7 articles about Dehydropipernonaline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 110-89-4
piperidine

: 177555-26-9
(2E,4E,8E)-9-benzo[1,3]dioxol-5-yl-nona-2,4,8-trienoic acid ethyl ester

: 107584-38-3
Dehydropipernonaline

Guidance literature:: With bis(bis(trimethylsilyl)amido)tin(II); In hexane; for 12h; Ambient temperature;
DOI:10.1139/v96-046

Reference yield:

: 120-57-0,30024-74-9
piperonal

: 107584-38-3
Dehydropipernonaline

Guidance literature:: Multi-step reaction with 7 steps

1: 1.) boron trifluoride etherate / 1.) THF, 0 deg C; 0 deg C to RT, 70 min; 2.) THF, RT, 14 h

2: 1.) LAH; 2.) NaOH, water / tetrahydrofuran / 1.) 0 deg C to RT, 3.5 h; 2.) RT, 20 min

3: 91 percent / triphenylphosphine, imidazole, iodine / diethyl ether; acetonitrile / 14 h / Ambient temperature

4: 93 percent / dimethylsulfoxide / 2 h / 8 °C

5: 79 percent / n-butyllithium / tetrahydrofuran; hexane / 1.5 h / 0 °C

6: 84 percent / glacial acetic acid, triphenylphosphine / toluene / 48 h / Heating

7: 88 percent / SN2 / hexane / 12 h / Ambient temperature

With 1H-imidazole; sodium hydroxide; lithium aluminium tetrahydride; n-butyllithium; boron trifluoride diethyl etherate; water; iodine; bis(bis(trimethylsilyl)amido)tin(II); acetic acid; triphenylphosphine; In tetrahydrofuran; diethyl ether; hexane; dimethyl sulfoxide; toluene; acetonitrile;
DOI:10.1139/v96-046

Reference yield:

: 107022-82-2
1-iodo-6-(3',4'-methylenedioxyphenyl)-5E-hexene

: 107584-38-3
Dehydropipernonaline

Guidance literature:: Multi-step reaction with 4 steps

1: 93 percent / dimethylsulfoxide / 2 h / 8 °C

2: 79 percent / n-butyllithium / tetrahydrofuran; hexane / 1.5 h / 0 °C

3: 84 percent / glacial acetic acid, triphenylphosphine / toluene / 48 h / Heating

4: 88 percent / SN2 / hexane / 12 h / Ambient temperature

With n-butyllithium; bis(bis(trimethylsilyl)amido)tin(II); acetic acid; triphenylphosphine; In tetrahydrofuran; hexane; dimethyl sulfoxide; toluene;
DOI:10.1139/v96-046