Benzenamine, 4,4'-azobis[N,N-dimethyl-

Base Information

• Chemical Name: Benzenamine, 4,4'-azobis[N,N-dimethyl-
• CAS No.: 6257-64-3
• Molecular Formula: C16H20 N4
• Molecular Weight: 268.362
• European Community (EC) Number: 228-388-9
• NSC Number: 9361
• DSSTox Substance ID: DTXSID6064169,DTXSID901043721
• Nikkaji Number: J60.391K,J2.436.744D
• Mol file: 6257-64-3.mol

Synonyms:DADAB;6257-64-3;p-N-Dimethylaminoazobenzene;4,4'-Bis(dimethylamino)azobenzene;Benzenamine, 4,4'-azobis[N,N-dimethyl-;p,p'-Azobis(N,N-dimethylaniline);N,N,N',N'-Tetramethyl-4,4'-azodianiline;CCRIS 2252;NSC 9361;EINECS 228-388-9;BRN 0750281;Diazene, bis(4-(dimethylamino)phenyl)-;Benzenamine, 4,4'-azobis(N,N-dimethyl-;Aniline, 4,4'-azobis(N,N-dimethyl-;ANILINE, p,p'-AZOBIS(N,N-DIMETHYL-;Benzenamine, 4,4'-(1,2-diazenediyl)bis(N,N-dimethyl-;Aniline, 4,4'-azobis[N,N-dimethyl-;Diazene, bis[4-(dimethylamino)phenyl]-;4-[[4-(dimethylamino)phenyl]diazenyl]-N,N-dimethylaniline;4-(4-dimethylaminophenyl)azo-N,N-dimethyl-aniline;SCHEMBL1405466;DTXSID6064169;NSC9361;Aniline,4'-azobis[N,N-dimethyl-;DTXSID901043721;NSC-9361;4,4'-Azo-bis(N,N-Dimethylanilin);Benzenamine,4'-azobis[N,N-dimethyl-;30926-05-7;LS-19575;(E)-N,N,N',N'-Tetramethylazobenzene-4,4'-diamine;4,4'-(1,2-Diazenediyl)bis[N,N-dimethylbenzenamine];4,4'-[(E)-1,2-Diazenediyl]bis(N,N-dimethylaniline)

Chemical Property of Benzenamine, 4,4'-azobis[N,N-dimethyl-

Chemical Property:

• Melting Point: 273oC
• Boiling Point: 426.6oC at 760 mmHg
• Flash Point: 211.8oC
• PSA: 31.20000
• Density: 1.02g/cm3
• LogP: 4.23400
• XLogP3: 4.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 268.16879665
• Heavy Atom Count: 20
• Complexity: 268

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C)C1=CC=C(C=C1)N=NC2=CC=C(C=C2)N(C)C

Technology Process of Benzenamine, 4,4'-azobis[N,N-dimethyl-

There total 39 articles about Benzenamine, 4,4'-azobis[N,N-dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4-amino-N,N-dimethylaniline (99-98-9) → methyl orange (6257-64-3)

Guidance literature:

With manganese(IV) oxide; In toluene; Reflux; Inert atmosphere;

DOI:10.1002/adsc.202100440

Reference yield: 85.0%

N,N-Dimethyl-4-nitroaniline (100-23-2) → methyl orange (6257-64-3)

Guidance literature:

With chloro-trimethyl-silane; samarium diiodide; tetra-(n-butyl)ammonium iodide; tert-butylammonium hexafluorophosphate(V); In tetrahydrofuran; at 20 ℃; for 5h; Electrochemical reaction;

DOI:10.1021/acscatal.7b02940

Reference yield: 50.0%

p-(dimethylamino)phenyl azide (18523-44-9) → methyl orange (6257-64-3)

Guidance literature:

With [^i-PrNDI]Ni₂(C₆H₆); In benzene; at 22 ℃; for 2h; Inert atmosphere; Sealed tube;

DOI:10.1021/jacs.8b00503

upstream raw materials:

1-allyl-3,4-methylenedioxybenzene

2,3-dimethyl-4-nitroso-aniline

N,N-dimethyl-aniline

4-amino-N,N-dimethylaniline

Downstream raw materials:

4-amino-N,N-dimethylaniline

N,N-Dimethyl-4-nitroaniline

methyl yellow

N'-(5-ethoxy-2-nitro-phenyl)-N,N-dimethyl-p-phenylenediamine