9,10-Epoxy-1,5-cyclododecadiene

Base Information

• Chemical Name: 9,10-Epoxy-1,5-cyclododecadiene
• CAS No.: 943-93-1
• Molecular Formula: C12H18 O
• Molecular Weight: 178.274
• Hs Code.: 2932999099
• European Community (EC) Number: 213-407-5
• Nikkaji Number: J208.486D
• Mol file: 943-93-1.mol

Synonyms:9,10-Epoxy-1,5-cyclododecadiene;943-93-1;(4Z,8Z)-13-oxabicyclo[10.1.0]trideca-4,8-diene;13-Oxabicyclo[10.1.0]trideca-4,8-diene;1,2-epoxycyclododeca-5,9-diene;13-Oxabicyclo(10.1.0)trideca-4,8-diene;epoxycyclododeca-5,9-diene;SCHEMBL328857;SCHEMBL328858;AKOS025295947;CS-0458887;13-Oxabicyclo[10.1.0]trideca-4,8-diene, AldrichCPR

Chemical Property of 9,10-Epoxy-1,5-cyclododecadiene

Chemical Property:

• Vapor Pressure: 0.0118mmHg at 25°C
• Boiling Point: 269.8°Cat760mmHg
• Flash Point: 113.6°C
• PSA: 12.53000
• Density: 0.941g/cm³
• LogP: 3.22040
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 178.135765193
• Heavy Atom Count: 13
• Complexity: 183

Purity/Quality:

99.9% ^*data from raw suppliers

1,2-EPOXY-5,6-TRANS-9,10-CIS-CYCLODODECADIENE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R36/38:Irritating to eyes and skin.
• Hazard Codes: R36/38:Irritating to eyes and skin.
• Statements: R36/38:Irritating to eyes and skin.
• Safety Statements: S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.; S36:Wear suitable prot

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CC=CCCC2C(O2)CCC=C1
• Isomeric SMILES: C1/C=C\CCC2OC2CC/C=C\C1

Technology Process of 9,10-Epoxy-1,5-cyclododecadiene

There total 11 articles about 9,10-Epoxy-1,5-cyclododecadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.7%

→ 9,10-Epoxy-1,5-cyclododecadiene (943-93-1,40702-89-4,40702-90-7,42539-84-4,55722-64-0,132200-29-4,138024-39-2)

Guidance literature:

Reference yield: 95.0%

(1E,5E,9Z)-cyclododeca-1,5,9-triene (706-31-0) → 1,2-epoxy-5,9-cyclododecadiene (943-93-1)

Guidance literature:

With phosphoric acid; sulfuric acid; dihydrogen peroxide; sodium tungstate; Aliquat 336; In water; 1,2-dichloro-ethane; at 70 ℃; for 1h; pH=1.6; microwave irradiation;

DOI:10.1080/00397910500278479

Reference yield: 85.0%

(1E,5E,9Z)-cyclododeca-1,5,9-triene (706-31-0) → epoxy E,Z-5,9-cyclododecadiene (943-93-1,40702-89-4,40702-90-7,42539-84-4,55722-64-0,132200-29-4,138024-39-2)

Guidance literature:

With Cumene hydroperoxide; molybdenum diacetylacetonate; In benzene; at 80 ℃; for 1h;

upstream raw materials:

(Z,Z,Z)-1,5,9-cyclododecatriene

(1E,5E,9Z)-cyclododeca-1,5,9-triene

cyclododeca-1,5,9-triene

Downstream raw materials:

cyclododecanol

1,2-epoxycyclododecane

cyclododecanone

cyclododeca-4,8-dien-1-one