Aluminum, tris(decyl)-

Base Information

• Chemical Name: Aluminum, tris(decyl)-
• CAS No.: 1726-66-5
• Molecular Formula: C30H63 Al
• Molecular Weight: 450.812
• Hs Code.: 2931900090
• European Community (EC) Number: 217-040-1
• UNII: 1YD433T62N
• DSSTox Substance ID: DTXSID5027431
• Wikidata: Q27253187
• Mol file: 1726-66-5.mol

Synonyms:Tridecylaluminum;Aluminum, tris(decyl)-;1726-66-5;Tris(decyl)aluminum;Tri-1-decylaluminum;Tri-n-decyl aluminum;Tris(n-decyl)aluminum;tris-decylalumane;TRI-N-DECYLALUMINUM;ALUMINUM TRI-N-DECYL;1YD433T62N;Tridecylaluminium;HSDB 5852;EINECS 217-040-1;UNII-1YD433T62N;tri-n-decyl-aluminum;DTXSID5027431;TRI-N-DECYLALUMINUM [HSDB];DB-043910;NS00082376;Q27253187

Chemical Property of Aluminum, tris(decyl)-

Chemical Property:

• Boiling Point: 174.9°Cat760mmHg
• Flash Point: 46.1°C
• PSA: 0.00000
• Density: g/cm³
• LogP: 12.22110
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 27
• Exact Mass: 450.4745154
• Heavy Atom Count: 31
• Complexity: 253

Purity/Quality:

99% ^*data from raw suppliers

ALUMINUM TRI-N-DECYL 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCC[Al](CCCCCCCCCC)CCCCCCCCCC

Technology Process of Aluminum, tris(decyl)-

There total 3 articles about Aluminum, tris(decyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

sodium aluminum tetrahydride + 1-Decene (872-05-9,17438-89-0,25189-70-2) + diisobutylaluminum chloride (1779-25-5) → tri-decylaluminum (1726-66-5)

Guidance literature:

In further solvent(s); byproducts: LiCl, isobutylene; NaAlH4, dec-1-ene loaded in a vertical-type ball mill under Ar or N2; mixt. agitated for 10 min at 70°C; (i-Bu)2AlCl added for 0.5 h; mixt. stored for 1.5 h at 95-100°C; isobutylene collected in a trap cooled with liq. N2; ppt. sepd.; filtrate heated for 1 h at 80°C (1 Torr); elem. anal.;

DOI:10.1023/A:1022412818827

Reference yield: 34.3%

aluminium hydride + 1-Decene (872-05-9,17438-89-0,25189-70-2) → tri-decylaluminum (1726-66-5)

Guidance literature:

With triethylaluminum; In hexane; (N2); heating (autoclave, 140°C, 30 min, 120°C, 6 h); distn.; elem. anal.;

Reference yield:

→ tri-decylaluminum (1726-66-5)

Guidance literature:

1-Decen, Triisobutyl-Al;

DOI:10.1007/BF00921156

upstream raw materials:

1-Decene

diisobutylaluminum chloride

Downstream raw materials:

decane

1-dodecene

(Z)-tridec-2-en-1-ols

Iododecane