5-Hexenal, 4-methyl-3-(phenylmethoxy)-, (3S,4S)-

Base Information

Chemical Name:5-Hexenal, 4-methyl-3-(phenylmethoxy)-, (3S,4S)-
CAS No.:850004-25-0
Molecular Formula:C14H18O2
Molecular Weight:218.296
Hs Code.:

Synonyms:

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Chemical Property of 5-Hexenal, 4-methyl-3-(phenylmethoxy)-, (3S,4S)-

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Technology Process of 5-Hexenal, 4-methyl-3-(phenylmethoxy)-, (3S,4S)-

There total 5 articles about 5-Hexenal, 4-methyl-3-(phenylmethoxy)-, (3S,4S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 850004-47-6
(3S,4S)-4-benzyloxy-6-hydroxy-3-methylhex-1-ene

: 850004-25-0
(3S,4S)-3-Benzyloxy-4-methyl-hex-5-enal

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; triethylamine; In dichloromethane; at -78 - 20 ℃; for 4h;
DOI:10.1021/ja062364i

Reference yield:

: 850004-46-5
(3S,4S)-4-benzyloxy-6-{[(tert-butyldimethyl)silyl]oxy}-3-methylhex-1-ene

: 850004-25-0
(3S,4S)-3-Benzyloxy-4-methyl-hex-5-enal

Guidance literature:: Multi-step reaction with 2 steps

1: 94 percent / tetrabutylammonium fluoride / tetrahydrofuran / 0.67 h / 20 °C

2: 95 percent / oxalyl chloride; DMSO; triethylamine / CH₂Cl₂ / 4 h / -78 - 20 °C

With oxalyl dichloride; tetrabutyl ammonium fluoride; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; dichloromethane; 2: Swern oxidation;
DOI:10.1021/ja062364i

Reference yield:

: 756834-72-7
(3S,4S)-3-methyl-6-<(tert-butyldimethylsilyl)oxy>-1-hexen-4-ol

: 850004-25-0
(3S,4S)-3-Benzyloxy-4-methyl-hex-5-enal

Guidance literature:: Multi-step reaction with 3 steps

1: 91 percent / NaHMDS / tetrahydrofuran; dimethylformamide / 2.5 h / 20 °C

2: 94 percent / tetrabutylammonium fluoride / tetrahydrofuran / 0.67 h / 20 °C

3: 95 percent / oxalyl chloride; DMSO; triethylamine / CH₂Cl₂ / 4 h / -78 - 20 °C

With oxalyl dichloride; tetrabutyl ammonium fluoride; sodium hexamethyldisilazane; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; 3: Swern oxidation;
DOI:10.1021/ja062364i