Technology Process of Benzenemethanamine, N-(5-phenyl-2-pentenyl)-
There total 1 articles about Benzenemethanamine, N-(5-phenyl-2-pentenyl)- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
propylamine; bis(1,5-cyclooctadiene)diiridium(I) dichloride; (S)-(+)-(3,5-dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)-bis-[(1S)-1-(2-methoxy-phenyl)ethyl]amine;
In
tetrahydrofuran;
at 20 ℃;
for 2h;
optical yield given as %ee;
regioselective reaction;
Inert atmosphere;
DOI:10.1002/anie.200802480
- Guidance literature:
-
1-acetyl-2,3-dihydro-1H-indol-3-one;
With
titanium(IV) isopropylate;
In
ethanol;
at 23 ℃;
for 0.5h;
Inert atmosphere;
C18H21N;
In
ethanol;
at 23 ℃;
for 12h;
Inert atmosphere;
With
sodium tris(acetoxy)borohydride;
In
ethanol;
for 1h;
Inert atmosphere;
DOI:10.1021/ja4095473
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: titanium(IV) isopropylate / ethanol / 0.5 h / 23 °C / Inert atmosphere
1.2: 12 h / 23 °C / Inert atmosphere
1.3: 1 h / Inert atmosphere
2.1: potassium carbonate / tetrahydrofuran; methanol / 0.5 h / 23 °C / Inert atmosphere
With
titanium(IV) isopropylate; potassium carbonate;
In
tetrahydrofuran; methanol; ethanol;
DOI:10.1021/ja4095473
