Imidazolidine, 2-(1,3-dimethyl-2-imidazolidinylidene)-1,3-dimethyl-

Base Information

• Chemical Name: Imidazolidine, 2-(1,3-dimethyl-2-imidazolidinylidene)-1,3-dimethyl-
• CAS No.: 1911-01-9
• Molecular Formula: C10H20 N4
• Molecular Weight: 196.296
• DSSTox Substance ID: DTXSID60172631
• Nikkaji Number: J1.052.861E
• Wikidata: Q83042729
• Mol file: 1911-01-9.mol

Synonyms:1911-01-9;2-(1,3-dimethylimidazolidin-2-ylidene)-1,3-dimethylimidazolidine;Imidazolidine, 2-(1,3-dimethyl-2-imidazolidinylidene)-1,3-dimethyl-;Imidazolidine,2-(1,3-dimethyl-2-imidazolidinylidene)-1,3-dimethyl-;SCHEMBL11101958;DTXSID60172631

Chemical Property of Imidazolidine, 2-(1,3-dimethyl-2-imidazolidinylidene)-1,3-dimethyl-

Chemical Property:

• Vapor Pressure: 0.0213mmHg at 25°C
• Boiling Point: 250.7°Cat760mmHg
• Flash Point: 95.7°C
• PSA: 12.96000
• Density: 1.063g/cm³
• LogP: -0.38100
• XLogP3: 1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 196.16879665
• Heavy Atom Count: 14
• Complexity: 211

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN1CCN(C1=C2N(CCN2C)C)C

Technology Process of Imidazolidine, 2-(1,3-dimethyl-2-imidazolidinylidene)-1,3-dimethyl-

There total 6 articles about Imidazolidine, 2-(1,3-dimethyl-2-imidazolidinylidene)-1,3-dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1,1',3,3'-tetramethyl-2,2'-biimidazolidine (96444-72-3) → 1,1',3,3'-tetramethyl-2,2'-biimidazolidinylidene (1911-01-9)

Guidance literature:

With potassium hexamethylsilazane; In benzene; Inert atmosphere;

DOI:10.1039/d0sc00699h

Reference yield:

1,3-Dimethyl-imidazolidine-2-tellone → 1,1',3,3'-tetramethyl-2,2'-biimidazolidinylidene (1911-01-9)

Guidance literature:

With petroleum; at 110 ℃; Yield given;

DOI:10.1039/c39800000635

Reference yield:

1,3-dimethylimidazolidin-2-ylidene (202584-80-3) → 1,1',3,3'-tetramethyl-2,2'-biimidazolidinylidene (1911-01-9)

Guidance literature:

at 60 ℃; under 0.1 Torr; Yield given;

DOI:10.1002/anie.199726071

upstream raw materials:

1,3-dimethylimidazolidin-2-ylidene

1,3-dimethylimidazolidine-2-thione

N,N-dimethyl-formamide dimethyl acetal

N,N`-dimethylethylenediamine

Downstream raw materials:

2-chloro-1,3-dimethylimidazolinium chloride

hexamesityldisilane

trimesitylgermane

trimesityl(methylthio)germane

Refernces

• 1、 Lappert, Michael F.,Martin, Tony R.. "Telluroureas and Derived Transition Metal Complexes: the Crystal and Molecular Structure of Et>>". . p. 635 - 637. Retrieved 1980.
• 2、 Rueping, Magnus,Nikolaienko, Pavlo,Lebedev, Yury,Adams, Alina. "Metal-free reduction of the greenhouse gas sulfur hexafluoride, formation of SF5 containing ion pairs and the application in fluorinations". supporting information. p. 2571 - 2575. Retrieved 2017/07/17.