Chemical Property of Francium
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Chemical Property:
- Melting Point:27°C
- Boiling Point:673°C (estimate)
- PSA：0.00000
- LogP:0.11250
- Hydrogen Bond Donor Count:0
- Hydrogen Bond Acceptor Count:0
- Rotatable Bond Count:0
- Exact Mass:223.01973
- Heavy Atom Count:1
- Complexity:0
- Purity/Quality:
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FRANCIUM 95.00% *data from reagent suppliers
Safty Information:
- Pictogram(s):
- Hazard Codes:
- MSDS Files:
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SDS file from LookChem
Useful:
- Chemical Classes:Physical/Radiation -> Radionuclides
- Canonical SMILES:[Fr]
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Description
Francium, the heaviest of the alkali metals, had been predicted on theoretical grounds and the properties of its compounds known with reasonable confidence for many years. Nevertheless, it remained on periodic charts only as element 87 until the French scientist, Marguerite Perey, discovered in 1939 that a short-lived isotope of element 87 with mass number 223 results from a-decay of actinium isotope 227, itself a decay product of U2. Actinium normally decays by emission, but 1 % of the actinium atoms undergo a-decay. Her experiments with this isotope were recognized as the first reliable evidence of the existence of element 87 and she chose the name francium in honor of her native France. No long-lived francium has been found in nature.It may be said that francium is not found in nature, since it exists only in short-lived radioactive forms. However, Fr223 is one of the daughter elements of U235 , so it must be considered to have transitory existence naturally, even for a very short life span. From the properties of the known isotopes, there is no reason to believe that a long-lived isotope will ever be found or synthesized.
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Physical properties
Francium, a radioactive member of Group 1 (the alkali metals) of the Periodic Table, has an atomic number of 87, an atomic weight of 223, a melting point of 27° and a boiling point of 677°. It has an oxidation state of +1. Over 20 isotopes of francium are known. The longest lived, 223Fr, obtained by a-disintegration of 227Ac (4.95 MeV), has a half-life of 22 min. This is the only isotope of francium that occurs naturally (in uranium minerals). Since there is less than 30g of francium at any time in the total crust of the earth, this element is not considered harmful or dangerous.
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Uses
The element francium is far too rare and far too radioactive to have any commercial applications. It does have some rather exotic scientific uses, however. Atoms of francium provide an excellent opportunity to examine many aspects of atomic and nuclear physics and even the theory that unifies the electromagnetic and the weak nuclear force into the electroweak force. Th ese experiments have been dubbed "table-top physics" to distinguish them from high-energy physics carried out in huge particle accelerators spanning vast distances the size of cities.
