1-methylazecane

Base Information

• Chemical Name: 1-methylazecane
• CAS No.: 6480-47-3
• Molecular Formula: C₁₀H₂₁N
• Molecular Weight: 155.283
• Mol file: 6480-47-3.mol

Synonyms:1-Methyldecahydroazecine

Chemical Property of 1-methylazecane

Chemical Property:

• Vapor Pressure: 0.235mmHg at 25°C
• Boiling Point: 206.6°Cat760mmHg
• Flash Point: 83.5°C
• Density: 0.823g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-methylazecane

There total 7 articles about 1-methylazecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-methyl-octahydro-azecin-5-one (61546-92-7) → N-Methyl-azacyclodecan (6480-47-3)

Guidance literature:

With hydrazine hydrate; diethylene glycol; anschliessend Erhitzen mit Kaliumhydroxid;

DOI:10.1021/ja01628a053

Reference yield:

1-methyloctahydroazecin-6-one (19641-26-0) → N-Methyl-azacyclodecan (6480-47-3)

Guidance literature:

With hydrazine hydrate; diethylene glycol; anschliessend Erhitzen mit Kaliumhydroxid;

DOI:10.1021/ja01628a053

Reference yield:

5,5'-methylimino-di-valeric acid diethyl ester (411218-95-6) → N-Methyl-azacyclodecan (6480-47-3)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium tert-butylate; xylene; aqueous HCl

2: diethylene glycol; hydrazine hydrate / anschliessend Erhitzen mit Kaliumhydroxid

With hydrogenchloride; potassium tert-butylate; hydrazine hydrate; xylene; diethylene glycol;

DOI:10.1021/ja01628a053

upstream raw materials:

1-methyl-octahydro-azecin-5-one

1-methyloctahydroazecin-6-one

4-methyl-octahydro-pyrrolo[1,2-a]azepinium; iodide

water