2-Pyrenemethanol

Base Information

Chemical Name:2-Pyrenemethanol
CAS No.:24471-48-5
Molecular Formula:C17H12 O
Molecular Weight:232.282
Hs Code.:2906299090
DSSTox Substance ID:DTXSID90179234
Nikkaji Number:J617.310A
Wikidata:Q83049735
Mol file:24471-48-5.mol

Synonyms:2-Pyrenemethanol;2-Hydroxymethylpyrene;2-(Hydroxymethyl)pyrene;24471-48-5;CCRIS 7295;BRN 2330710;4-06-00-05008 (Beilstein Handbook Reference);SCHEMBL9609744;DTXSID90179234;LS-129446

Suppliers and Price of 2-Pyrenemethanol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
2-HYDROXYMETHYLPYRENE 95.00%
5MG
$ 505.77

Total 12 raw suppliers

Chemical Property of 2-Pyrenemethanol

Chemical Property:

Vapor Pressure:4.46E-09mmHg at 25°C
Refractive Index:1.4500 (estimate)
Boiling Point:455.2°Cat760mmHg
Flash Point:207.5°C
PSA：20.23000
Density:1.321g/cm³
LogP:4.07630
XLogP3:4.1
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:232.088815002
Heavy Atom Count:18
Complexity:287

Purity/Quality:

99% ^*data from raw suppliers

2-HYDROXYMETHYLPYRENE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC2=C3C(=C1)C=CC4=C3C(=CC(=C4)CO)C=C2

Technology Process of 2-Pyrenemethanol

There total 7 articles about 2-Pyrenemethanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 36373-11-2
pyrene-2-carboxylic acid methyl ester

: 24471-48-5
2-hydroxymethylpyrene

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether; for 2h; Heating;
DOI:10.1002/chem.200601498

Reference yield:

: 26933-87-9
pyrene-2-carboxaldehyde

: 24471-48-5
2-hydroxymethylpyrene

Guidance literature:: With lithium aluminium tetrahydride;
DOI:10.1021/jo9707343

Reference yield:

: 781-17-9
4,5,9,10-tetrahydropyrene

: 24471-48-5
2-hydroxymethylpyrene

Guidance literature:: Multi-step reaction with 3 steps

1.1: bromine / N,N-dimethyl-formamide / 6 h / 20 °C

1.2: 4 h / Reflux; Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran; diethyl ether; hexane / 2 h / -78 °C

2.2: 16 h / -30 - 20 °C

3.1: sodium tetrahydroborate / tetrahydrofuran / 20 °C

With sodium tetrahydroborate; n-butyllithium; bromine; In tetrahydrofuran; diethyl ether; hexane; N,N-dimethyl-formamide;
DOI:10.1039/c4ob01183j