4-Methyl-2-methylidene-1,3-dioxolane

Base Information

• Chemical Name: 4-Methyl-2-methylidene-1,3-dioxolane
• CAS No.: 85079-89-6
• Molecular Formula: C5H8O2
• Molecular Weight: 100.11600
• Hs Code.: 2932999099
• DSSTox Substance ID: DTXSID30533972
• Nikkaji Number: J138.644A
• Mol file: 85079-89-6.mol

Synonyms:85079-89-6;4-Methyl-2-methylidene-1,3-dioxolane;1,3-Dioxolane, 4-methyl-2-methylene-;2-Methylene-4-methyl-1,3-dioxolane;SCHEMBL3945747;DTXSID30533972;methylene-4-methyl-1,3-dioxolane

Chemical Property of 4-Methyl-2-methylidene-1,3-dioxolane

Chemical Property:

• PSA: 18.46000
• LogP: 0.89290
• XLogP3: 1.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 100.052429494
• Heavy Atom Count: 7
• Complexity: 88.1

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1COC(=C)O1

Technology Process of 4-Methyl-2-methylidene-1,3-dioxolane

There total 1 articles about 4-Methyl-2-methylidene-1,3-dioxolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

4-methyl-1,3-dioxolan-2-ylmethyl chloride (16390-83-3) → 4-methyl-2-methylene-1,3-dioxolane (85079-89-6)

Guidance literature:

With potassium tert-butylate; Aliquat 336; In tetrahydrofuran; at 20 ℃; Heating;

DOI:10.1021/jo990227g

Reference yield: 77.0%

phenyl isocyanate (103-71-9) + 4-methyl-2-methylene-1,3-dioxolane (85079-89-6) → 2-methyl-6-phenyl-1,4-dioxa-6-azaspiro<4.3>octan-7-one (116424-07-8)

Guidance literature:

In tetrahydrofuran; for 4h; Ambient temperature;

DOI:10.1016/S0040-4039(00)86050-5

Reference yield:

4-methyl-2-methylene-1,3-dioxolane (85079-89-6) + thiophenol (108-98-5) → 2,4-dimethyl-2-(phenylthio)-1,3-dioxolane (90369-21-4)

Guidance literature:

In tetrachloromethane; at 0 ℃; Yield given;

DOI:10.1021/ja00326a026

upstream raw materials:

4-methyl-1,3-dioxolan-2-ylmethyl chloride

Downstream raw materials:

2-methyl-6-phenyl-1,4-dioxa-6-azaspiro<4.3>octan-7-one

2,4-dimethyl-2-(phenylthio)-1,3-dioxolane

1-methyl-2-(phenylthio)ethyl acetate

2-(phenylthio)propyl acetate