2,2-Dichloroethenylsulfonylbenzene

Base Information

• Chemical Name: 2,2-Dichloroethenylsulfonylbenzene
• CAS No.: 3559-73-7
• Molecular Formula: C8H6Cl2O2S
• Molecular Weight: 237.106
• NSC Number: 512592
• DSSTox Substance ID: DTXSID10325594
• Mol file: 3559-73-7.mol

Synonyms:3559-73-7;((2,2-Dichlorovinyl)sulfonyl)benzene;2,2-dichloroethenylsulfonylbenzene;NSC512592;dichlorovinyl phenyl sulfone;DTXSID10325594;NSC 512592;NSC-512592;Benzene, [(2,2-dichloroethenyl)sulfonyl]-

Chemical Property of 2,2-Dichloroethenylsulfonylbenzene

Chemical Property:

• Vapor Pressure: 0.000182mmHg at 25°C
• Boiling Point: 339.4°Cat760mmHg
• Flash Point: 159°C
• Density: 1.446g/cm³
• XLogP3: 2.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 235.9465560
• Heavy Atom Count: 13
• Complexity: 280

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)S(=O)(=O)C=C(Cl)Cl

Technology Process of 2,2-Dichloroethenylsulfonylbenzene

There total 8 articles about 2,2-Dichloroethenylsulfonylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

1,1-dichloro-2-phenylthioethene (3559-72-6) → phenyl 2,2-dichlorovinyl sulfone (3559-73-7)

Guidance literature:

With dihydrogen peroxide; In acetic acid; for 6h; Heating;

Reference yield: 63.2%

2,2,2-trichloroethyl phenyl sulfone (6618-71-9) → phenyl 2,2-dichlorovinyl sulfone (3559-73-7)

Guidance literature:

With triethylamine; In benzene; for 4h; Heating;

Reference yield:

thiophenol (108-98-5) → phenyl 2,2-dichlorovinyl sulfone (3559-73-7)

Guidance literature:

Multi-step reaction with 2 steps

1: (PhCO)2O₂

2: H₂O₂ / acetic acid

With dihydrogen peroxide; dibenzoyl peroxide; In acetic acid;

DOI:10.1021/ja00965a038

upstream raw materials:

1,1-dichloro-2-phenylthioethene

2,2,2-trichloroethyl phenyl sulfone

thiophenol

2,2,2-trichloroethyl phenyl sulfide

Downstream raw materials:

2-Benzenesulfonyl-N,N'-bis-(2-fluoro-phenyl)-acetamidine

C₂₂H₂₂N₂O₄S

2-benzenesulfonylmethyl-benzooxazole

N,N'-Di(p-bromophenyl)phenylsulfonylacetamidin