2-Oxazolidinone, 3-[(2S,3R,5R)-3-methoxy-2-[(4-methoxyphenyl)methoxy]-1-oxo-5-[(trieth ylsilyl)oxy]-7-octenyl]-4-(phenylmethyl)-, (4S)-

Base Information

Chemical Name:2-Oxazolidinone, 3-[(2S,3R,5R)-3-methoxy-2-[(4-methoxyphenyl)methoxy]-1-oxo-5-[(trieth ylsilyl)oxy]-7-octenyl]-4-(phenylmethyl)-, (4S)-
CAS No.:851102-16-4
Molecular Formula:C33H47NO7Si
Molecular Weight:597.824
Hs Code.:

Synonyms:

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Chemical Property of 2-Oxazolidinone, 3-[(2S,3R,5R)-3-methoxy-2-[(4-methoxyphenyl)methoxy]-1-oxo-5-[(trieth ylsilyl)oxy]-7-octenyl]-4-(phenylmethyl)-, (4S)-

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Technology Process of 2-Oxazolidinone, 3-[(2S,3R,5R)-3-methoxy-2-[(4-methoxyphenyl)methoxy]-1-oxo-5-[(trieth ylsilyl)oxy]-7-octenyl]-4-(phenylmethyl)-, (4S)-

There total 1 articles about 2-Oxazolidinone, 3-[(2S,3R,5R)-3-methoxy-2-[(4-methoxyphenyl)methoxy]-1-oxo-5-[(trieth ylsilyl)oxy]-7-octenyl]-4-(phenylmethyl)-, (4S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 851102-06-2
(S)-4-Benzyl-3-[(2S,3R,5R)-3-hydroxy-2-(4-methoxy-benzyloxy)-5-triethylsilanyloxy-oct-7-enoyl]-oxazolidin-2-one

: 420-37-1
trimethoxonium tetrafluoroborate

: 851102-16-4
(S)-4-Benzyl-3-[(2S,3R,5R)-3-methoxy-2-(4-methoxy-benzyloxy)-5-triethylsilanyloxy-oct-7-enoyl]-oxazolidin-2-one

Guidance literature:: In dichloromethane; at 20 ℃; for 15h;
DOI:10.1021/ol050070g

Reference yield:

: 851102-16-4
(S)-4-Benzyl-3-[(2S,3R,5R)-3-methoxy-2-(4-methoxy-benzyloxy)-5-triethylsilanyloxy-oct-7-enoyl]-oxazolidin-2-one

: 851102-17-5
(S)-4-Benzyl-3-((2S,3R,5R)-2-hydroxy-3-methoxy-5-triethylsilanyloxy-oct-7-enoyl)-oxazolidin-2-one

Guidance literature:: With water; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; at 0 - 20 ℃; for 2.33333h;
DOI:10.1021/ol050070g

Reference yield:

: 851102-16-4
(S)-4-Benzyl-3-[(2S,3R,5R)-3-methoxy-2-(4-methoxy-benzyloxy)-5-triethylsilanyloxy-oct-7-enoyl]-oxazolidin-2-one

: 851102-11-9
4-benzyl-3-(4-{6-[6-(tert-butyl-dimethyl-silanyloxy)-4-methoxy-2-methoxymethoxy-1,1,7-trimethyl-9-triisopropylsilanyloxymethyl-undec-7-enyl]-4-oxo-3,4-dihydro-2H-pyran-2-yl}-3-methoxy-2-methoxymethoxy-butyryl)-oxazolidin-2-one

Guidance literature:: Multi-step reaction with 6 steps

1.1: H₂O; DDQ / CH₂Cl₂ / 2.33 h / 0 - 20 °C

2.1: 62 mg / DIPEA / CH₂Cl₂ / 15 h / 20 °C

3.1: pyridine; O₃ / CH₂Cl₂ / -78 °C

3.2: PPh₃ / CH₂Cl₂ / 4 h / 20 °C

4.1: iPr₂NH; nBuLi / hexane; tetrahydrofuran / 1 h / -78 °C

4.2: tetrahydrofuran; hexane / 0.02 h / -78 °C

5.1: 141 mg / Dess-Martin periodinane; pyridine / CH₂Cl₂ / 4 h / 0 °C

6.1: 62 percent / p-TsOH / toluene / 2.5 h / 45 °C

With pyridine; n-butyllithium; water; Dess-Martin periodane; toluene-4-sulfonic acid; ozone; diisopropylamine; N-ethyl-N,N-diisopropylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; hexane; dichloromethane; toluene; 5.1: Dess-Martin oxidation;
DOI:10.1021/ol050070g