1-Piperidinecarboxylic acid, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-6-oxo-3,4,5-tris(phenylmethoxy)-, 1,1-dimethylethyl ester, (2S,3S,4S,5R)-

Base Information

Chemical Name:1-Piperidinecarboxylic acid, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-6-oxo-3,4,5-tris(phenylmethoxy)-, 1,1-dimethylethyl ester, (2S,3S,4S,5R)-
CAS No.:851220-62-7
Molecular Formula:C37H49NO7Si
Molecular Weight:647.884
Hs Code.:

1-Piperidinecarboxylic acid,
2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-6-oxo-3,4,5-tris(phenylmethoxy)-,
1,1-dimethylethyl ester, (2S,3S,4S,5R)-

Synonyms:

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Chemical Property of 1-Piperidinecarboxylic acid, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-6-oxo-3,4,5-tris(phenylmethoxy)-, 1,1-dimethylethyl ester, (2S,3S,4S,5R)-

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Technology Process of 1-Piperidinecarboxylic acid, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-6-oxo-3,4,5-tris(phenylmethoxy)-, 1,1-dimethylethyl ester, (2S,3S,4S,5R)-

There total 4 articles about 1-Piperidinecarboxylic acid, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-6-oxo-3,4,5-tris(phenylmethoxy)-, 1,1-dimethylethyl ester, (2S,3S,4S,5R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 851220-60-5
(3R,4S,5S,6R)-3,4,5-Tris-benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-piperidin-2-one

: 24424-99-5
di-tert-butyl dicarbonate

: 851220-62-7
3,4,5-tris-benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-6-oxo-piperidine-1-carboxylic acid tert-butyl ester

Guidance literature:: With dmap; In acetonitrile;
DOI:10.1016/j.tetlet.2005.02.057

Reference yield:

: 851220-59-2
(3R,4S,5S)-3,4,5-Tris-benzyloxy-6-hydroxy-piperidin-2-one

: 851220-62-7
3,4,5-tris-benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-6-oxo-piperidine-1-carboxylic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: imidazole

2: 100 percent / DMAP / acetonitrile

With 1H-imidazole; dmap; In acetonitrile;
DOI:10.1016/j.tetlet.2005.02.057

Reference yield:

: 851220-58-1
(2R,3S,4R,5R)-2,3,4-Tris-benzyloxy-5,6-dihydroxy-hexanoic acid amide

: 851220-62-7
3,4,5-tris-benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-6-oxo-piperidine-1-carboxylic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: NaIO₄; silica gel / CH₂Cl₂; H₂O

1.2: 95 percent / tetrahydrofuran; aq. HCl

2.1: imidazole

3.1: 100 percent / DMAP / acetonitrile

With 1H-imidazole; dmap; sodium periodate; silica gel; In dichloromethane; water; acetonitrile;
DOI:10.1016/j.tetlet.2005.02.057