4-(Benzyloxy)-6-broMo-1,3-benzodioxole

Base Information

Chemical Name:4-(Benzyloxy)-6-broMo-1,3-benzodioxole
CAS No.:852123-08-1
Molecular Formula:C14H11BrO3
Molecular Weight:307.144
Hs Code.:
Mol file:852123-08-1.mol

Synonyms:

Suppliers and Price of 4-(Benzyloxy)-6-broMo-1,3-benzodioxole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
4-(Benzyloxy)-6-bromo-1,3-benzodioxole 95+%
1g
$ 427.00

Chemenu
4-(Benzyloxy)-6-bromo-1,3-benzodioxole 95%
1g
$ 399.00

Alichem
4-(Benzyloxy)-6-bromo-1,3-benzodioxole
1g
$ 418.46

AK Scientific
4-(Benzyloxy)-6-bromo-1,3-benzodioxole
1g
$ 636.00

Total 4 raw suppliers

Chemical Property of 4-(Benzyloxy)-6-broMo-1,3-benzodioxole

Chemical Property:

PSA：27.69000
LogP:3.75680

Purity/Quality:

97% ^*data from raw suppliers

4-(Benzyloxy)-6-bromo-1,3-benzodioxole 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 4-(Benzyloxy)-6-broMo-1,3-benzodioxole

There total 2 articles about 4-(Benzyloxy)-6-broMo-1,3-benzodioxole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 852123-27-4
3-(benzyloxy)-5-bromo-1,2-dihydroxybenzene

: 74-97-5
chlorobromomethane

: 852123-08-1
4-benzyloxy-6-bromo-benzo[1,3]dioxole

Guidance literature:: With potassium carbonate; In N,N-dimethyl-formamide; at 100 ℃; for 3h;
DOI:10.1021/ol050476t

Reference yield:

: 697302-70-8
3-(benzyloxy)-5-bromo-2-hydroxybenzaldehyde

: 852123-08-1
4-benzyloxy-6-bromo-benzo[1,3]dioxole

Guidance literature:: Multi-step reaction with 2 steps

1: 83 percent / H₂O₂; NaOH / H₂O / 3 h / 25 °C

2: 96 percent / K₂CO₃ / dimethylformamide / 3 h / 100 °C

With sodium hydroxide; dihydrogen peroxide; potassium carbonate; In water; N,N-dimethyl-formamide; 1: Dakin oxidation;
DOI:10.1021/ol050476t

Reference yield:

: 852123-08-1
4-benzyloxy-6-bromo-benzo[1,3]dioxole

: 6-[(1S,2S)-4-(9-Bora-bicyclo[3.3.1]non-9-yl)-1-(tert-butyl-dimethyl-silanyloxy)-2,3-dimethyl-butyl]-5-bromo-4-methoxy-benzo[1,3]dioxole

: ((1S,2S)-4-(4-(benzoyloxy)benzo[d][1,3]dioxol-6-yl)-1-(5-bromo-4-methoxybenzo[d][1,3]dioxol-6-yl)-2,3-dimethylbutoxy)(tert-butyl)dimethylsilane

Guidance literature:: With sodium hydroxide; triphenylphosphine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; water; at 70 ℃; for 22h;
DOI:10.1021/ol050476t