4,4'-(1,1,3,3-Tetramethyldisiloxane-1,3-diyl)dianiline

Base Information

Chemical Name:4,4'-(1,1,3,3-Tetramethyldisiloxane-1,3-diyl)dianiline
CAS No.:85214-57-9
Molecular Formula:C16H24N2OSi2
Molecular Weight:316.55
Hs Code.:
DSSTox Substance ID:DTXSID80544997
Nikkaji Number:J675.489I
Wikidata:Q82422343

Synonyms:85214-57-9;SCHEMBL127697;4,4'-(1,1,3,3-Tetramethyldisiloxane-1,3-diyl)dianiline;DTXSID80544997;1,3-bis(4-aminophenyl)tetramethyldisiloxane

Suppliers and Price of 4,4'-(1,1,3,3-Tetramethyldisiloxane-1,3-diyl)dianiline

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 7 raw suppliers

Chemical Property of 4,4'-(1,1,3,3-Tetramethyldisiloxane-1,3-diyl)dianiline

Chemical Property:

Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:316.14271646
Heavy Atom Count:21
Complexity:301

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C[Si](C)(C1=CC=C(C=C1)N)O[Si](C)(C)C2=CC=C(C=C2)N

Technology Process of 4,4'-(1,1,3,3-Tetramethyldisiloxane-1,3-diyl)dianiline

There total 7 articles about 4,4'-(1,1,3,3-Tetramethyldisiloxane-1,3-diyl)dianiline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 102368-08-1
(4-aminophenyl)dimethylsilanol

: 85214-57-9
4,4'-(1,1,3,3-tetramethyl-1,3-disiloxanediyl)bis(benzenamine)

Guidance literature:: With tetra(n-butyl)ammonium hydroxide; In acetonitrile; for 48h; Ambient temperature;
DOI:10.1021/jo00363a006

Reference yield: 56.0%

: 85214-57-9
4,4'-(1,1,3,3-tetramethyl-1,3-disiloxanediyl)bis(benzenamine)

Guidance literature:

Reference yield:

: 5089-33-8
2-(4-bromophenyl)-1,1,1,3,3,3-hexamethyldisilazane

: 85214-57-9
4,4'-(1,1,3,3-tetramethyl-1,3-disiloxanediyl)bis(benzenamine)

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) Mg, I₂ / 1.) THF, RT, 20 min, 2.) THF, RT, overnight

2: 82 percent / triethylamine / 1.5 h / Ambient temperature

3: 91 percent / H₂O / acetone / 48 h / 80 °C

4: 91 percent / 1.0 M aq. tetrabutylammonium hydroxide (TBAH) / acetonitrile / 48 h / Ambient temperature

With tetra(n-butyl)ammonium hydroxide; water; iodine; magnesium; triethylamine; In acetone; acetonitrile;
DOI:10.1021/jo00363a006