2H-Pyran, tetrahydro-2-(10-tetradecynyloxy)-

Base Information

Chemical Name:2H-Pyran, tetrahydro-2-(10-tetradecynyloxy)-
CAS No.:86252-54-2
Molecular Formula:C19H34O2
Molecular Weight:294.478
Hs Code.:

Synonyms:10-Tetradecyn-1-ol THP ether;2H-Pyran,tetrahydro-2-(10-tetradecynyloxy);1-tetrahydropyranyloxy-10-tetradecyne;1-(tetrahydropyran-2'-yloxy)tetradec-10-yne;

Suppliers and Price of 2H-Pyran, tetrahydro-2-(10-tetradecynyloxy)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Tetrahydro-2-(10-tetradecyn-1-yloxy)-2H-pyran
250mg
$ 965.00

Total 0 raw suppliers

Chemical Property of 2H-Pyran, tetrahydro-2-(10-tetradecynyloxy)-

Chemical Property:

PSA：18.46000
LogP:5.45390

Purity/Quality:: Tetrahydro-2-(10-tetradecyn-1-yloxy)-2H-pyran ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Uses Tetrahydro-2-(10-tetradecyn-1-yloxy)-2H-pyran is an intermediate in the synthesis of cyclopropyl containing fatty acids as mechanistic probes for cytochromes P450.

Technology Process of 2H-Pyran, tetrahydro-2-(10-tetradecynyloxy)-

There total 7 articles about 2H-Pyran, tetrahydro-2-(10-tetradecynyloxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 51953-88-9,151329-50-9
1-[(tetrahydropyran-2-yl)oxy]undec-10-yne

: 106-94-5
propyl bromide

: 86252-54-2
1-(tetrahydropyran-2'-yloxy)tetradec-10-yne

Guidance literature:: 1-[(tetrahydropyran-2-yl)oxy]undec-10-yne; With n-butyllithium; In tetrahydrofuran; at -40 ℃; for 2h;

propyl bromide; With N,N,N,N,N,N-hexamethylphosphoric triamide; In tetrahydrofuran; at -40 - 20 ℃;
DOI:10.1021/jo047985d

Reference yield:

: 55362-80-6
9-bromononan-1-ol

: 86252-54-2
1-(tetrahydropyran-2'-yloxy)tetradec-10-yne

Guidance literature:: Multi-step reaction with 2 steps

1: p-TsOH / diethyl ether

2: 1.) 2M BuLi / 1.) hexane, HMPT, 0 deg C, 30 min, 2.)THF, r. t., 12 h

With n-butyllithium; toluene-4-sulfonic acid; In diethyl ether;

Reference yield:

: 110-87-2
3,4-dihydro-2H-pyran

: 86252-54-2
1-(tetrahydropyran-2'-yloxy)tetradec-10-yne

Guidance literature:: Multi-step reaction with 2 steps

1: p-TsOH / diethyl ether

2: 1.) 2M BuLi / 1.) hexane, HMPT, 0 deg C, 30 min, 2.)THF, r. t., 12 h

With n-butyllithium; toluene-4-sulfonic acid; In diethyl ether;