Methyl 7-oxabicyclo[2.2.1]hept-2-ene-2-carboxylate

Base Information

Chemical Name:Methyl 7-oxabicyclo[2.2.1]hept-2-ene-2-carboxylate
CAS No.:86708-65-8
Molecular Formula:C₈H₁₀O₃
Molecular Weight:154.166
Hs Code.:
DSSTox Substance ID:DTXSID10518424
Mol file:86708-65-8.mol

Synonyms:Methyl 7-oxabicyclo[2.2.1]hept-2-ene-2-carboxylate;86708-65-8;Methyl7-oxabicyclo[2.2.1]hept-2-ene-2-carboxylate;SCHEMBL7716358;DTXSID10518424;MFCD30489531;SY267394;F52822

Suppliers and Price of Methyl 7-oxabicyclo[2.2.1]hept-2-ene-2-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

AK Scientific
Methyl7-oxabicyclo[2.2.1]hept-2-ene-2-carboxylate
1g
$ 1680.00

Total 5 raw suppliers

Chemical Property of Methyl 7-oxabicyclo[2.2.1]hept-2-ene-2-carboxylate

Chemical Property:

PSA：35.53000
LogP:0.64700
XLogP3:0.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:154.062994177
Heavy Atom Count:11
Complexity:219

Purity/Quality:

99% ^*data from raw suppliers

Methyl7-oxabicyclo[2.2.1]hept-2-ene-2-carboxylate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=CC2CCC1O2

Technology Process of Methyl 7-oxabicyclo[2.2.1]hept-2-ene-2-carboxylate

There total 2 articles about Methyl 7-oxabicyclo[2.2.1]hept-2-ene-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: methyl 2-phenylthio-7-oxabicyclo<2.2.1>heptane-2-carboxylate

: 86708-65-8
methyl 7-oxabicyclo<2.2.1>hept-2-ene-2-carboxylate

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 1h;

Reference yield: 85.0%

: 943828-20-4
methyl 3-bromo-7-oxabicyclo[2.2.1]hept-2-ene-2-carboxylate

: 86708-65-8
methyl 7-oxabicyclo<2.2.1>hept-2-ene-2-carboxylate

Guidance literature:: With acetic acid; zinc; In water; at 0 - 20 ℃; for 0.2h;

Reference yield:

: 86708-65-8
methyl 7-oxabicyclo<2.2.1>hept-2-ene-2-carboxylate

: (1R*,2R*,3S*,4S*)-N-(3,4-dichlorophenyl)-3-(pyridin-4-yl)-7-oxabicyclo[2.2.1]heptane-2-carboxamide

Guidance literature:: Multi-step reaction with 2 steps

1: 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; potassium carbonate; chloro(1,5-cyclooctadiene)rhodium(I) dimer / water; 1,4-dioxane / 1 h / 100 °C / Inert atmosphere; Microwave irradiation

2: 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide; N-ethyl-N,N-diisopropylamine; silica gel / ethyl acetate; N,N-dimethyl-formamide / 0.75 h / 80 °C

With chloro(1,5-cyclooctadiene)rhodium(I) dimer; silica gel; potassium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide; N-ethyl-N,N-diisopropylamine; In 1,4-dioxane; water; ethyl acetate; N,N-dimethyl-formamide;