Gold, (3-ethenylphenyl)(triphenylphosphine)-

Base Information

• Chemical Name: Gold, (3-ethenylphenyl)(triphenylphosphine)-
• CAS No.: 870485-37-3
• Molecular Formula: C26H22AuP
• Molecular Weight: 562.401
• Mol file: 870485-37-3.mol

Synonyms:

Chemical Property of Gold, (3-ethenylphenyl)(triphenylphosphine)-

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Gold, (3-ethenylphenyl)(triphenylphosphine)-

There total 1 articles about Gold, (3-ethenylphenyl)(triphenylphosphine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + 3-bromostyrene (2039-86-3,25584-47-8) → m-vinylphenyl(triphenylphosphine)gold(I) (870485-37-3)

Guidance literature:

With n-C₄H₉Li; In tetrahydrofuran; n-BuLi added dropwise at -78°C to soln. of 3-bromostyrene in THF in Schlenk techniques under Ar; mixt. stirred for 10 min, soln. ClAuPPh3in THF added; mixt. warmed to room temp., mixed for 16 h; treated with satd. soln. of NH4Cl, extd. with Et2O; org. layers washed with satd. soln. of NaCl, dried over MgSO4; solvents removed under vac.; crystals obtained via crystn. from CHCl3;

DOI:10.1016/j.jorganchem.2005.07.080

upstream raw materials:

(triphenylphosphine)gold(I) chloride

3-bromostyrene